{"id":"W2268211278","doi":"10.1007/s13361-016-1343-y","title":"Examining the Influence of Phosphorylation on Peptide Ion Structure by Ion Mobility Spectrometry-Mass Spectrometry","year":2016,"lang":"en","type":"article","venue":"Journal of the American Society for Mass Spectrometry","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"Sciex (Canada)","funders":"National Institute of General Medical Sciences; National Institutes of Health","keywords":"Phosphopeptide; Chemistry; Peptide; Ion-mobility spectrometry; Mass spectrometry; Phosphorylation; Moiety; Ion; Intramolecular force; Protein mass spectrometry; Ion-mobility spectrometry–mass spectrometry; Tandem mass spectrometry; Crystallography; Analytical Chemistry (journal); Stereochemistry; Chromatography; Biochemistry; Selected reaction monitoring; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.001160984,0.0005377642,0.0009609663,0.000245249,0.0004106971,0.00008325542,0.001754837,0.0002120669,0.0007588263],"category_scores_gemma":[0.0006184911,0.0003001111,0.00142867,0.002604274,0.000845827,0.0002916526,0.0001527078,0.001062469,0.000002917173],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001314417,"about_ca_system_score_gemma":0.0001583197,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004007658,"about_ca_topic_score_gemma":0.000001912596,"domain_scores_codex":[0.9959765,0.00009792981,0.001272403,0.0006072478,0.001295367,0.0007505464],"domain_scores_gemma":[0.9930827,0.001304084,0.003607369,0.001408405,0.0004070092,0.0001904188],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002019658,0.0001865101,0.009074377,0.00007249171,0.0003698863,7.127628e-7,0.00007182013,0.00006831114,0.9826905,0.001577775,0.004810865,0.0008747815],"study_design_scores_gemma":[0.001014851,0.001102118,0.03322312,0.0002194738,0.0002618642,0.0000505491,0.0009627967,0.00005322305,0.9398533,0.02055568,0.002228908,0.0004741683],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9815392,0.0002790295,0.01375422,0.002445974,0.0001323652,0.0004010008,0.0003735335,0.00007956998,0.0009951178],"genre_scores_gemma":[0.9673969,0.0005155574,0.03059364,0.0002869012,0.0005783177,0.00003067717,0.000008850344,0.0000831272,0.0005060885],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04283726,"threshold_uncertainty_score":0.9999451,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009957050075035405,"score_gpt":0.2542561313106309,"score_spread":0.2442990812355954,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}