{"id":"W2270054988","doi":"10.1021/acs.jpcc.5b08595","title":"Polymerization of Nitrogen in Ammonium Azide at High Pressures","year":2015,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Diamond and Carbon-based Materials Research","field":"Materials Science","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"China Postdoctoral Science Foundation; Ministry of Science and Technology of the People's Republic of China; Ministry of Education of the People's Republic of China; National Natural Science Foundation of China","keywords":"Nitrogen; Polymerization; Azide; Ammonium; Chemistry; Molecular dynamics; Polymer chemistry; Annealing (glass); Liquid nitrogen; Materials science; Computational chemistry; Organic chemistry; Polymer; Composite material","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005223178,0.00007715677,0.0002150174,0.00001611986,0.00002020746,0.00001834753,0.0003364199,0.00003166077,0.00009039701],"category_scores_gemma":[0.0001173653,0.00004829284,0.00004837883,0.00009416383,0.0001235752,0.00008862901,0.00009388696,0.00008993004,0.000008597915],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004536852,"about_ca_system_score_gemma":0.00011323,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008647783,"about_ca_topic_score_gemma":0.000001446915,"domain_scores_codex":[0.9989629,0.0001026907,0.0002543911,0.00006507546,0.0004568324,0.0001580962],"domain_scores_gemma":[0.9992973,0.0001023123,0.0002281682,0.0001503762,0.0001261756,0.00009572156],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004448067,0.0001053289,0.0001728806,0.00004114425,0.000006207465,0.000004646105,0.0002112674,0.0007479979,0.9980159,0.00001728729,0.0001835465,0.00004898054],"study_design_scores_gemma":[0.0004020975,0.00007243359,0.0001188861,0.00003239685,0.00001849836,0.000008297408,0.00007521625,0.0001014987,0.9974404,0.001634187,0.00004585007,0.00005025942],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9990557,0.0001571351,0.000008774145,0.0001235415,0.00004892428,0.00003514356,0.00001299284,0.000004269578,0.0005535092],"genre_scores_gemma":[0.9995639,0.000007179561,0.00002117053,0.0000112483,0.0002994286,0.000001297873,0.000001976052,0.000007923136,0.00008591589],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0016169,"threshold_uncertainty_score":0.1969325,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01317758232416455,"score_gpt":0.2577231774515301,"score_spread":0.2445455951273655,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}