{"id":"W2270054988","doi":"10.1021/acs.jpcc.5b08595","title":"Polymerization of Nitrogen in Ammonium Azide at High Pressures","year":2015,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Diamond and Carbon-based Materials Research","field":"Materials Science","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"China Postdoctoral Science Foundation; Ministry of Science and Technology of the People's Republic of China; Ministry of Education of the People's Republic of China; National Natural Science Foundation of China","keywords":"Nitrogen; Polymerization; Azide; Ammonium; Chemistry; Molecular dynamics; Polymer chemistry; Annealing (glass); Liquid nitrogen; Materials science; Computational chemistry; Organic chemistry; Polymer; Composite material","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008908101,0.0002174965,0.0002513324,0.000170914,0.0003918079,0.0003337252,0.0002332971,0.000285941,0.001686716],"category_scores_gemma":[0.0002016082,0.0001841452,0.0002187919,0.000129104,0.0003404,0.0003835917,0.0002117141,0.0003179056,0.0001193746],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006664615,"about_ca_system_score_gemma":0.0005124066,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004487477,"about_ca_topic_score_gemma":0.003158908,"domain_scores_codex":[0.9999496,0.000005272049,0.000001315735,0.000008618355,0.00001869883,0.00001655244],"domain_scores_gemma":[0.9999558,0.00001828436,0.000007898831,0.00000253963,0.000006831091,0.000008748812],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004676207,0.0002545995,0.005087992,0.000520142,0.00009985822,0.000806272,0.0004808147,0.5445585,0.4186863,0.02039898,0.001019173,0.007619815],"study_design_scores_gemma":[0.0001661039,0.0002839022,0.002947271,0.00002272228,0.00002744723,0.00007919361,0.00007159229,0.8972864,0.09414588,0.002979144,0.00196495,0.00002554647],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9938665,0.0001341316,0.001524436,0.0000923913,0.00001390147,0.00001198641,0.00006892542,0.0000387667,0.004248987],"genre_scores_gemma":[0.9979569,0.0001499171,0.001081594,0.00001564875,0.000004184463,0.00001210025,0.00008237726,0.00001670045,0.0006806605],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004487477,"threshold_uncertainty_score":0.008922756,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01317758232416455,"score_gpt":0.2577231774515301,"score_spread":0.2445455951273655,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}