{"id":"W2270422525","doi":"10.1021/acs.inorgchem.5b02788","title":"Electron-Transfer Kinetics within Supramolecular Assemblies of Donor Tetrapyrrolytic Dyes and an Acceptor Palladium Cluster","year":2016,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal; Université de Sherbrooke","funders":"Fonds de recherche du Québec – Nature et technologies; Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Photochemistry; Ultrafast laser spectroscopy; Electron transfer; Quenching (fluorescence); Acceptor; Reactivity (psychology); Kinetics; Excited state; Porphyrin; Electron acceptor; Fluorescence; Spectroscopy","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001177292,0.0002108732,0.0002081556,0.00009022152,0.0001186471,0.0002653186,0.0003009482,0.0002165087,0.0006990313],"category_scores_gemma":[0.0002640878,0.0001326801,0.0001163667,0.00009503951,0.0001673268,0.0002550492,0.0001873556,0.0003652662,0.0002263154],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003671625,"about_ca_system_score_gemma":0.0001102311,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004988239,"about_ca_topic_score_gemma":0.000496566,"domain_scores_codex":[0.9999036,0.00001017064,0.000004524973,0.0000330461,0.00002505608,0.0000236036],"domain_scores_gemma":[0.9999111,0.00001958977,0.00002278064,0.000007703407,0.00001320062,0.00002564273],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008745796,0.00001924908,0.0001759508,0.0000239795,0.00000716599,0.00002697207,0.00003393806,0.0002287269,0.9982815,0.00009456342,0.00001872673,0.001001806],"study_design_scores_gemma":[0.000009495178,0.0001675457,0.001211203,0.000002206183,0.00001328368,0.00004052878,0.00001634795,0.003196362,0.9949881,0.00002235217,0.0003278774,0.000004687968],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9985845,0.000109799,0.001005606,0.000008145991,0.000003598232,0.000004392246,0.00001639334,0.0000299832,0.0002375965],"genre_scores_gemma":[0.9989346,0.00007104017,0.0005375748,0.000004550073,0.000001045442,0.000005976248,0.00003316343,0.00000699904,0.0004050174],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006990313,"threshold_uncertainty_score":0.00266397,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007917470538718281,"score_gpt":0.2338892991295972,"score_spread":0.225971828590879,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}