{"id":"W2270523251","doi":"10.1093/jaoac/85.5.1112","title":"Temperature-Sensitive Resolution of cis- and trans-Fatty Acid Isomers of Partially Hydrogenated Vegetable Oils on SP-2560 and CP-Sil 88 Capillary Columns","year":2002,"lang":"en","type":"article","venue":"Journal of AOAC International","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":46,"is_retracted":false,"has_abstract":true,"ca_institutions":"Health Canada","funders":"","keywords":"Isothermal process; Cis–trans isomerism; Structural isomer; Chemistry; Analytical Chemistry (journal); Resolution (logic); Chromatography; Materials science; Stereochemistry; Thermodynamics; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001652207,0.0001401513,0.0003019243,0.00008308285,0.00005298847,0.00002101402,0.0001253241,0.0001506421,0.000357379],"category_scores_gemma":[0.00007882348,0.0001288199,0.0001610421,0.0001025414,0.000206673,0.0001389271,0.00002049787,0.0003269662,8.123115e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004012185,"about_ca_system_score_gemma":0.00003013767,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008661763,"about_ca_topic_score_gemma":0.000003427085,"domain_scores_codex":[0.9987246,0.00002097038,0.0005292002,0.0001491055,0.0004369936,0.0001390721],"domain_scores_gemma":[0.9990071,0.00008851293,0.0003901557,0.00009250605,0.000302628,0.0001190782],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003763343,0.0002488619,0.00258431,0.0001128312,0.0004874558,0.00006230739,0.0002700961,0.0001572937,0.9948526,0.0001559746,0.00054069,0.0001512527],"study_design_scores_gemma":[0.001165232,0.0001481136,0.001169814,0.0002656837,0.0001056101,0.000236426,0.0001837709,0.002100708,0.9940861,0.0001142952,0.0003031065,0.000121133],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9931274,0.000778198,0.00005759223,0.000348622,0.00006727493,0.0000235866,0.00006874678,0.000005844337,0.005522756],"genre_scores_gemma":[0.9988195,0.0006250953,0.0001926846,0.00005623275,0.0001366362,6.958062e-7,0.00001105858,0.00001027458,0.000147871],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005692073,"threshold_uncertainty_score":0.5253123,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009131962510044805,"score_gpt":0.2126569157991007,"score_spread":0.2035249532890559,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}