{"id":"W2275614953","doi":"10.1021/jacs.5b09311","title":"Cyclopropanation/Carboboration Reactions of Enynes with B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>","year":2015,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":88,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Studienstiftung des Deutschen Volkes; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Verband der Chemischen Industrie; Alexander von Humboldt-Stiftung","keywords":"Cyclopropanation; Chemistry; Moiety; Cyclopropane; Alkene; Cyclopentane; Lewis acids and bases; Stereospecificity; Alkyne; Stereochemistry; Ring (chemistry); Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001332457,0.0004631966,0.0002009787,0.0001157111,0.0002432579,0.0002026478,0.0002785616,0.0002472852,0.002774726],"category_scores_gemma":[0.0001791265,0.000114683,0.0001580393,0.0001648075,0.0001797825,0.0002539275,0.0002753868,0.0003760341,0.0006108921],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002446127,"about_ca_system_score_gemma":0.0001992521,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009384374,"about_ca_topic_score_gemma":0.001964754,"domain_scores_codex":[0.9999056,0.00001190087,0.000006319735,0.00001792631,0.00001752466,0.00004074124],"domain_scores_gemma":[0.9999459,0.0000120909,0.00001537564,0.000008739645,0.000007879694,0.00001006579],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003352923,0.00005577466,0.000373414,0.0002305532,0.00002459309,0.0001797085,0.0001041133,0.000324956,0.9882908,0.001676655,0.0003955702,0.008008526],"study_design_scores_gemma":[0.00001599527,0.0001604744,0.000518991,0.000005596057,0.000005949029,0.0001715839,0.00001990272,0.0003155053,0.9955481,0.0001003543,0.003131021,0.000006514138],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9809117,0.001651734,0.00511748,0.00009329552,0.00007388663,0.00008573093,0.0002617181,0.0001336602,0.01167082],"genre_scores_gemma":[0.9946977,0.0008229488,0.002219799,0.00003010183,0.000005964668,0.00002681515,0.0001975653,0.00002557415,0.001973627],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002774726,"threshold_uncertainty_score":0.009282351,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009455289843574187,"score_gpt":0.2252081395674387,"score_spread":0.2157528497238645,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}