{"id":"W2277721675","doi":"10.1002/chem.201600219","title":"Transition‐Metal‐Free Coupling of Alkynes with α‐Bromo Carbonyl Compounds: An Efficient Approach towards β,γ‐Alkynoates and Allenoates","year":2016,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Fonds Québécois de la Recherche sur la Nature et les Technologies; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Transition metal; Coupling (piping); Chemistry; Transition (genetics); Polymer chemistry; Materials science; Organic chemistry; Metallurgy; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0009784908,0.0003365042,0.0003866222,0.00005509878,0.0002127972,0.0001083569,0.0004596259,0.00006834479,0.0007649149],"category_scores_gemma":[0.0001937737,0.0002353685,0.0001183242,0.0001458184,0.0004196598,0.0001480138,0.0001024991,0.0002935354,0.000002812282],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008576154,"about_ca_system_score_gemma":0.0001281798,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004122587,"about_ca_topic_score_gemma":3.219779e-7,"domain_scores_codex":[0.997999,0.00005664866,0.0006212585,0.0004621073,0.0005330442,0.0003279564],"domain_scores_gemma":[0.9982484,0.0001286997,0.0004017577,0.0005554095,0.0003298559,0.000335896],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002187823,0.0002803933,0.000247426,0.0003983428,0.0001967668,0.00006577973,0.0007359629,0.003252871,0.9919974,0.00002073727,0.0001477968,0.002437735],"study_design_scores_gemma":[0.009366442,0.0002202175,0.000943996,0.001241134,0.0005532712,0.007679059,0.004053846,0.03875777,0.9326336,0.0001856203,0.002994715,0.001370323],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9625835,0.0005530729,0.02763763,0.0002130215,0.00005247961,0.00005450497,0.0001061634,0.0000923823,0.008707215],"genre_scores_gemma":[0.9894924,0.00009874477,0.008971862,0.00002431847,0.0004504609,0.00000376748,0.0000585095,0.00009028814,0.0008097116],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0593638,"threshold_uncertainty_score":0.9598047,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02201067779107383,"score_gpt":0.2310824240104278,"score_spread":0.2090717462193539,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}