{"id":"W2280332516","doi":"10.1039/c5sc04904k","title":"A fascinating multifaceted redox-active chelating ligand: introducing the N,N′-dimethyl-3,3′-biquinoxalinium “methylbiquinoxen” platform","year":2016,"lang":"en","type":"article","venue":"Chemical Science","topic":"Synthesis and Biological Evaluation","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Nautical Research Society","funders":"Alexander von Humboldt-Stiftung","keywords":"Redox; Ligand (biochemistry); Chelation; Chemistry; Combinatorial chemistry; Nanotechnology; Materials science; Biochemistry; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002361428,0.0003115032,0.0001620636,0.00009449558,0.0001896324,0.0002568656,0.000636032,0.0005202539,0.001876837],"category_scores_gemma":[0.0001320887,0.0001376115,0.0001142242,0.00007340455,0.000221136,0.0003622159,0.0002990268,0.0003540124,0.0007055646],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003329018,"about_ca_system_score_gemma":0.0002046757,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006250187,"about_ca_topic_score_gemma":0.0009354348,"domain_scores_codex":[0.9999301,0.00001440485,0.000003607798,0.00002268168,0.00001471982,0.0000145681],"domain_scores_gemma":[0.9999689,0.000004844938,0.000008558101,0.000003068077,0.000005345272,0.000009276505],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001324236,0.00001555221,0.00003726451,0.0001209005,0.000004298568,0.0000568847,0.00003221602,0.0001623625,0.9917304,0.001897151,0.0005381369,0.005272459],"study_design_scores_gemma":[0.00003233185,0.0003556977,0.000258784,0.0000145608,0.00001330833,0.0002445941,0.00002722036,0.001507629,0.974533,0.0003500875,0.02264265,0.0000200266],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8612036,0.01069826,0.09555455,0.002473832,0.0004538468,0.0002210213,0.0007953247,0.001062763,0.02753678],"genre_scores_gemma":[0.9464668,0.00261187,0.03726334,0.0006144455,0.00005462449,0.0001241784,0.000439111,0.00006145176,0.01236422],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001876837,"threshold_uncertainty_score":0.006278634,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03259824895447681,"score_gpt":0.2884358479208231,"score_spread":0.2558375989663462,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}