{"id":"W2282007788","doi":"10.1080/10426500108546612","title":"Formation of Two Novel <sup>t</sup>BuNSe(μ-N<sup>t</sup>Bu)<sub>2</sub>EO<sub>x</sub> (E = S, x = 2; E = Se, x = 1) Heterocycles","year":2001,"lang":"en","type":"article","venue":"Phosphorus, sulfur, and silicon and the related elements","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chalcogen; Nitrogen; Chemistry; Molecule; X-ray crystallography; Crystallography; Selenium; Cycloaddition; Bond length; Nuclear magnetic resonance spectroscopy; Stereochemistry; Diffraction; Crystal structure; Organic chemistry; Catalysis; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006058978,0.0001657896,0.0001280479,0.000117255,0.0001437481,0.0002227975,0.0001904257,0.0001532159,0.001381762],"category_scores_gemma":[0.00009302921,0.00009903707,0.00009457266,0.00008313193,0.0001746104,0.0001360907,0.0001955568,0.0001304735,0.0002377277],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001690469,"about_ca_system_score_gemma":0.0001776897,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002408548,"about_ca_topic_score_gemma":0.000898366,"domain_scores_codex":[0.9999484,0.00000689755,0.000003970907,0.00001302728,0.00001344135,0.00001423116],"domain_scores_gemma":[0.9999471,0.000006162706,0.0000134708,0.000006789374,0.000009728056,0.00001673254],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006411797,0.00001274054,0.0002258044,0.00004327253,0.000005703317,0.0001078166,0.00002412026,0.0001668431,0.9954255,0.0005534219,0.00005963591,0.00331105],"study_design_scores_gemma":[0.00002221284,0.0002255457,0.0009358086,0.000002496356,0.000007742276,0.0002047357,0.00001760717,0.0004257653,0.9954273,0.00007211238,0.002655524,0.00000324199],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9916864,0.000442711,0.003676879,0.00003390758,0.00002126935,0.00004504602,0.0001073103,0.00006877141,0.003917729],"genre_scores_gemma":[0.9912738,0.0002550427,0.004236434,0.00002537119,0.000004860786,0.00003927297,0.0002046166,0.00002046223,0.003940285],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001381762,"threshold_uncertainty_score":0.004622459,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01254722369217306,"score_gpt":0.2205718490238512,"score_spread":0.2080246253316782,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}