{"id":"W2283488790","doi":"10.1021/acs.organomet.5b00763","title":"Preparation, Structural Analysis, and Reactivity Studies of Phosphenium Dications","year":2015,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"Grand Équipement National De Calcul Intensif; Agency for Science, Technology and Research","keywords":"Chemistry; Reactivity (psychology); Computational chemistry; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001718846,0.0003179502,0.000278041,0.0001545731,0.0002282125,0.0001815532,0.0002859088,0.000276965,0.001331615],"category_scores_gemma":[0.0003227459,0.0001636596,0.0001676641,0.0001993366,0.0002024838,0.0002481071,0.0002581607,0.0005088756,0.0002678406],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002427688,"about_ca_system_score_gemma":0.0001195677,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003252283,"about_ca_topic_score_gemma":0.0005803956,"domain_scores_codex":[0.9998422,0.00002248532,0.0000157788,0.00004659129,0.00004632616,0.00002666747],"domain_scores_gemma":[0.9999131,0.00001253956,0.00002007059,0.00001863388,0.00002073539,0.00001500774],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001262165,0.00001544733,0.0001284265,0.0001080004,0.0000113804,0.0001201516,0.0000690345,0.0003491184,0.9958695,0.0002309777,0.00008346191,0.002888308],"study_design_scores_gemma":[0.00001350645,0.0003054445,0.0005762952,0.000002678822,0.00001036426,0.0001984028,0.00001507423,0.000379833,0.9964738,0.00004563699,0.001971184,0.000007757928],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9932678,0.0007237145,0.003025347,0.00005470216,0.00001626656,0.0000365523,0.0002520608,0.00003784117,0.002585934],"genre_scores_gemma":[0.9931216,0.0006955601,0.0044313,0.00003825641,0.000008030934,0.00001879321,0.000418725,0.00002177964,0.00124594],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001331615,"threshold_uncertainty_score":0.004454732,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0447597151802973,"score_gpt":0.3150119439505237,"score_spread":0.2702522287702264,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}