{"id":"W2284762343","doi":"10.1002/ejic.201600285","title":"Long‐Lived, Emissive Excited States in Direct and Amide‐Linked Thienyl‐Substituted Ru<sup>II</sup> Complexes","year":2016,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Amide; Ruthenium; Excited state; Cover (algebra); Bipyridine; Center (category theory); Metal; Group (periodic table); Crystallography; Stereochemistry; Catalysis; Crystal structure; Organic chemistry; Atomic physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002391196,0.0002217259,0.0002573362,0.0001782105,0.0003193872,0.0005119221,0.0007700209,0.0003991802,0.004610726],"category_scores_gemma":[0.0003039014,0.0001685545,0.0001409347,0.0002073747,0.0004689208,0.0003119715,0.0002898111,0.0005379372,0.0003701753],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006375241,"about_ca_system_score_gemma":0.0001120144,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008161709,"about_ca_topic_score_gemma":0.000962048,"domain_scores_codex":[0.9998616,0.00002272874,0.000003689567,0.00003634343,0.00002305964,0.00005265499],"domain_scores_gemma":[0.9998485,0.00007817453,0.00002585747,0.00001459437,0.00001333053,0.00001949726],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001593123,0.0001247243,0.001297437,0.0002672267,0.00004271119,0.0005427168,0.0005373529,0.001743051,0.9820284,0.002656803,0.0009481786,0.008218318],"study_design_scores_gemma":[0.00008944431,0.0006856603,0.007557564,0.00003136717,0.00004253618,0.0003123057,0.0002354482,0.005747611,0.9830549,0.0002895636,0.001929291,0.00002434679],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9948134,0.0003295115,0.0007496297,0.00005154048,0.000008784845,0.000005035104,0.00005887978,0.00004652304,0.003936625],"genre_scores_gemma":[0.997481,0.0001282798,0.000311803,0.00002110607,0.000003283011,0.000008481345,0.00008322128,0.00001864796,0.001944189],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004610726,"threshold_uncertainty_score":0.01542437,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01321293357053212,"score_gpt":0.2200888692093393,"score_spread":0.2068759356388072,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}