{"id":"W2285050241","doi":"10.1002/0471264180.or074.02","title":"Oxoammonium‐ and Nitroxide‐Catalyzed Oxidations of Alcohols","year":2009,"lang":"en","type":"other","venue":"Organic reactions","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":120,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"","keywords":"Chemistry; Nitroxide mediated radical polymerization; Catalysis; Disproportionation; Radical; Alcohol oxidation; Electron paramagnetic resonance; Aqueous solution; Redox; Stoichiometry; Organic chemistry; Primary (astronomy); Nitroxyl; Polymer chemistry; Photochemistry; Polymerization; Radical polymerization","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002651458,0.0006067377,0.000244189,0.0002983857,0.00008562587,0.0002081221,0.0002865337,0.0002764835,0.0007870286],"category_scores_gemma":[0.0002167196,0.0001731451,0.0002893465,0.0002304527,0.0001407379,0.0003870313,0.0003297466,0.0004601065,0.0004036385],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003322826,"about_ca_system_score_gemma":0.0001612748,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003698897,"about_ca_topic_score_gemma":0.000563075,"domain_scores_codex":[0.9998431,0.0000337714,0.00001610114,0.00003163578,0.00003917802,0.00003613719],"domain_scores_gemma":[0.9999413,0.00001052052,0.00001885169,0.000004320271,0.00001742639,0.000007563729],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002386469,0.0001122262,0.0006917074,0.006961881,0.0001612776,0.0008026353,0.0002929121,0.002866654,0.8831766,0.01214801,0.001560415,0.09098708],"study_design_scores_gemma":[0.0000141383,0.0002909208,0.0009950357,0.0001837253,0.00006048274,0.0005085922,0.00004270241,0.0007038675,0.9296411,0.0008102756,0.06673288,0.00001620164],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"review","genre_gemma":"empirical","genre_scores_codex":[0.4243717,0.5167166,0.02941564,0.0005719135,0.001422738,0.0001583063,0.0003747468,0.0001606849,0.02680779],"genre_scores_gemma":[0.69095,0.2814556,0.008216599,0.0002604019,0.0002562938,0.0001042796,0.0003672441,0.00004258317,0.01834703],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.0007870286,"threshold_uncertainty_score":0.002632856,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01017413802099149,"score_gpt":0.2383274374485785,"score_spread":0.228153299427587,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}