{"id":"W2287127436","doi":"10.1021/acs.organomet.5b00835","title":"Inner- and Outer-Sphere Roles of Ruthenium Phosphido Complexes in the Hydrophosphination of Alkenes","year":2015,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Ruthenium; Cationic polymerization; Phosphine; Cycloaddition; Catalytic cycle; Alkene; Coordination sphere; Catalysis; Hexene; Nucleophile; Medicinal chemistry; Photochemistry; Stereochemistry; Polymer chemistry; Organic chemistry; Molecule; Ethylene","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002866716,0.0001098878,0.0002358326,0.00009311963,0.00002154704,0.00001631313,0.0002516002,0.000074143,0.0002072825],"category_scores_gemma":[0.000135019,0.00008240647,0.00005178331,0.0006886338,0.0001046834,0.00008858644,0.00006494243,0.00007866138,0.000005333573],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002415739,"about_ca_system_score_gemma":0.00003626226,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008844103,"about_ca_topic_score_gemma":0.00006676157,"domain_scores_codex":[0.9990861,0.0000230699,0.0003250663,0.0001456836,0.0003146319,0.0001054943],"domain_scores_gemma":[0.9993082,0.00007694519,0.0001998012,0.0002609488,0.0001101098,0.00004394615],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003006329,0.003643218,0.1943244,0.001364797,0.001042046,0.00004348572,0.06031333,0.001214488,0.5035296,0.04733168,0.00184038,0.185052],"study_design_scores_gemma":[0.002183397,0.00009385023,0.005230395,0.0000505874,0.0001910477,0.00002239935,0.01455347,0.003169677,0.9496245,0.003600624,0.02083989,0.0004401887],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9906704,0.001611236,0.0001025458,0.0002549376,0.00001804318,0.00004584383,0.00002408516,0.00001272291,0.007260123],"genre_scores_gemma":[0.9992412,0.0001174097,0.0001760386,0.00003762632,0.00002206212,0.000005017174,0.00005213021,0.00001267517,0.0003358722],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4460949,"threshold_uncertainty_score":0.3360438,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0184278035845337,"score_gpt":0.234012428274374,"score_spread":0.2155846246898403,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}