{"id":"W2288643332","doi":"10.1039/c6cp00890a","title":"A blue 4′,7-diaminoflavylium cation showing an extended pH range stability","year":2016,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Nautical Research Society","funders":"Université de Bordeaux; Centre National de la Recherche Scientifique","keywords":"Chemistry; Kinetic energy; Amine gas treating; Kinetics; Chemical stability; Thermodynamics; Diagram; Computational chemistry; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001073909,0.0006626641,0.0006672984,0.000007272822,0.0001834336,0.00005533565,0.00069317,0.0002574947,0.0004444074],"category_scores_gemma":[0.0001573001,0.0005412411,0.0004057436,0.0002221122,0.0004837831,0.0004636209,0.0001533384,0.0005575493,0.00004410931],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003628941,"about_ca_system_score_gemma":0.0001107238,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000147705,"about_ca_topic_score_gemma":7.216232e-7,"domain_scores_codex":[0.9967588,0.0000242612,0.000456432,0.001194818,0.0006013315,0.0009643871],"domain_scores_gemma":[0.9977686,0.0003073256,0.0001327709,0.001122463,0.0002030348,0.0004657439],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001925266,0.001320508,0.0001551869,0.0004324165,0.0001036863,0.000005167968,0.0004409518,0.000001525809,0.991827,0.00009211339,0.0001012989,0.005327631],"study_design_scores_gemma":[0.001249481,0.00002147675,0.00002738725,0.00009043726,0.0001093003,0.000006111711,0.0001173146,0.0002770018,0.9917798,0.005266384,0.0002750017,0.0007803116],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9898575,0.00005552634,0.0007535167,0.0002352228,0.000028549,0.0001144582,0.0001846699,0.0004529244,0.008317665],"genre_scores_gemma":[0.9970748,0.00001725504,0.00005516021,0.00005220872,0.002057955,0.0002118381,0.0001720964,0.00008030458,0.0002783476],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008039317,"threshold_uncertainty_score":0.9997039,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02204978020420723,"score_gpt":0.252398160656211,"score_spread":0.2303483804520037,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}