{"id":"W2289772327","doi":"10.1021/acs.analchem.5b04097","title":"Improved Steroids Detection and Evidence for Their Regiospecific Decompositions Using Anion Attachment Mass Spectrometry","year":2016,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Division of Chemistry; Centre National de la Recherche Scientifique; World Anti-Doping Agency","keywords":"Chemistry; Ion-mobility spectrometry; Electrospray ionization; Mass spectrometry; Fluoride; Adduct; Chromatography; Medicinal chemistry; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000762381,0.0007367756,0.0002580379,0.0004911424,0.0002412839,0.0003334539,0.0004933567,0.0006012956,0.001516445],"category_scores_gemma":[0.001241534,0.0002567295,0.0002584905,0.000376368,0.0005539694,0.0003097822,0.0003231936,0.0005517007,0.000447818],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002362193,"about_ca_system_score_gemma":0.0002880539,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006698786,"about_ca_topic_score_gemma":0.0008114069,"domain_scores_codex":[0.9989707,0.0002670596,0.00006136206,0.0002345868,0.0003335394,0.0001327501],"domain_scores_gemma":[0.9992686,0.0002622048,0.0001903116,0.00007833136,0.0001475072,0.00005309935],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008828651,0.000007055713,0.0003191875,0.00002531357,0.000005336695,0.00004215886,0.00002735192,0.00002251345,0.9980779,0.00005176842,0.00001528105,0.001317832],"study_design_scores_gemma":[0.000003143519,0.00007761249,0.0009508806,0.000002578979,0.000005860652,0.0001649254,0.00001301635,0.0001683166,0.9978977,0.00002572922,0.0006858911,0.000004364581],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9389717,0.004672825,0.05149974,0.0002026927,0.0000655164,0.0001161015,0.0004901578,0.0003329359,0.003648304],"genre_scores_gemma":[0.9586936,0.002078715,0.03548551,0.0002151103,0.00003115474,0.00007041456,0.0004772407,0.00005488652,0.002893481],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001516445,"threshold_uncertainty_score":0.005072951,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04460822640436539,"score_gpt":0.3218728682430786,"score_spread":0.2772646418387132,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}