{"id":"W2291442626","doi":"10.3762/bjoc.12.25","title":"Regioselective palladium-catalyzed ring-opening reactions of C1-substituted oxabicyclo[2,2,1]hepta-2,5-diene-2,3-dicarboxylates","year":2016,"lang":"en","type":"article","venue":"Beilstein Journal of Organic Chemistry","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Regioselectivity; Steric effects; Palladium; Ring (chemistry); Yield (engineering); Medicinal chemistry; Aryl; Catalysis; Biphenyl; Diene; Structural isomer; Electronic effect; Stereochemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003981323,0.0004618862,0.0008204553,0.0001470026,0.0001616672,0.00004633427,0.000789808,0.0003977953,0.00572441],"category_scores_gemma":[0.001270524,0.0003701397,0.0004352631,0.0005121206,0.0002161129,0.0004100755,0.0001526723,0.000676956,0.00003220475],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007338892,"about_ca_system_score_gemma":0.0006003711,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001462981,"about_ca_topic_score_gemma":0.000006711941,"domain_scores_codex":[0.9966658,0.00003891806,0.001497765,0.0004830708,0.0007730129,0.0005414849],"domain_scores_gemma":[0.9954979,0.000357575,0.002105979,0.0007541524,0.0008886333,0.0003957178],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002209359,0.0001485522,0.0006627893,0.000309377,0.0003960566,0.00008724928,0.0002927611,0.000005696844,0.9941161,0.0000312983,0.00006197122,0.003667262],"study_design_scores_gemma":[0.002645257,0.00003763181,0.0002153166,0.0009267961,0.0002389384,0.00162622,0.0009759431,0.000005675316,0.9896884,0.0002371289,0.002979414,0.0004233037],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9901068,0.0008491251,0.0008216944,0.0003092092,0.0002518007,0.00008715496,0.00003005427,0.0001083991,0.007435791],"genre_scores_gemma":[0.9960334,0.0004357657,0.0009865834,0.000007458054,0.0005983695,0.000007005036,0.00001000823,0.0001038668,0.001817593],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005926579,"threshold_uncertainty_score":0.9998751,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01061159302176823,"score_gpt":0.2220128146177635,"score_spread":0.2114012215959952,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}