{"id":"W2291723412","doi":"10.1002/cjce.22435","title":"Methanol carboxylation over zirconium dioxide: Effect of catalyst phase composition on its acid‐base spectrum and direction of catalytic transformations","year":2016,"lang":"en","type":"article","venue":"The Canadian Journal of Chemical Engineering","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Catalysis; Calcination; Zirconium dioxide; Carboxylation; Methanol; Chemistry; Base (topology); Inorganic chemistry; Tetragonal crystal system; Zirconium; Selectivity; Acid–base reaction; Phase (matter); Bicarbonate; Chemical engineering; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003401134,0.0001763383,0.0003737152,0.0003586741,0.00002872021,0.0000125938,0.0001601455,0.0001041428,0.00002761483],"category_scores_gemma":[0.0003543133,0.0001243827,0.0001639188,0.0003536581,0.00008934875,0.0002160957,0.000009322037,0.0002103224,0.00000128429],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003345998,"about_ca_system_score_gemma":0.000078803,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003513683,"about_ca_topic_score_gemma":0.00006601468,"domain_scores_codex":[0.9988185,0.00002695801,0.0005749982,0.0001122596,0.000260907,0.000206399],"domain_scores_gemma":[0.9988546,0.0003615627,0.0002324458,0.0001921538,0.0001058154,0.0002533613],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005638334,0.00001085664,0.00003789265,0.0001224806,0.0001136292,0.000003210044,0.0001693433,0.007025831,0.9914054,0.0003803671,0.000008139201,0.0006665189],"study_design_scores_gemma":[0.001221575,0.0000807065,0.00005147843,0.0002990139,0.0001922098,0.00005166776,0.000003985105,0.01962043,0.9783225,0.000016143,0.00001735422,0.00012293],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9908058,0.0003260525,0.008059284,0.0003547607,0.000147481,0.000141161,0.00007713013,0.00001916477,0.00006915581],"genre_scores_gemma":[0.9998035,0.000007809372,0.0000461073,0.000006227461,0.00008266838,0.000005331528,0.00001459204,0.00002677537,0.000006985298],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01308284,"threshold_uncertainty_score":0.5072179,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00846921713265963,"score_gpt":0.2247785599381971,"score_spread":0.2163093428055375,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}