{"id":"W2293276788","doi":"10.1039/c5ra27955k","title":"A pH-driven molecular shuttle based on rotaxane-bridged periodic mesoporous organosilicas with responsive release of guests","year":2016,"lang":"en","type":"article","venue":"RSC Advances","topic":"Mesoporous Materials and Catalysis","field":"Materials Science","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Light Source (Canada); Saskatoon Medical Imaging","funders":"National Research Council Canada; Natural Sciences and Engineering Research Council of Canada; National Natural Science Foundation of China","keywords":"Mesoporous organosilica; Rotaxane; PMOS logic; Chemistry; Combinatorial chemistry; Mesoporous material; Chemical engineering; Materials science; Nanotechnology; Mesoporous silica; Organic chemistry; Supramolecular chemistry; Molecule; Catalysis; Physics; Engineering","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001121772,0.0002413131,0.0001639721,0.0001104277,0.00006814553,0.000163197,0.0001771205,0.0002339655,0.0005731715],"category_scores_gemma":[0.0001267616,0.000128785,0.0001647942,0.00006171089,0.0001923217,0.0002922414,0.0001333773,0.0002421553,0.0001620982],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001499936,"about_ca_system_score_gemma":0.0001062818,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001961011,"about_ca_topic_score_gemma":0.0002624692,"domain_scores_codex":[0.9999487,0.000005013441,0.00000410554,0.00001853887,0.000009308716,0.00001433938],"domain_scores_gemma":[0.9999211,0.00001699297,0.00002587301,0.000008521021,0.000008509538,0.00001911047],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000444299,0.000006631969,0.0000610409,0.00002548221,0.000002900516,0.00002699249,0.000007675344,0.00006300498,0.9988562,0.0001173298,0.00001940119,0.0007689863],"study_design_scores_gemma":[0.000008816175,0.0001434842,0.0005621068,0.000001361195,0.000005449461,0.00005530478,0.000004573732,0.0006328712,0.9978825,0.00001673563,0.0006824965,0.000004258611],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9937528,0.0003851246,0.004987401,0.00004624707,0.00003372462,0.0000252873,0.00008927374,0.0001718102,0.0005083684],"genre_scores_gemma":[0.9962573,0.0001521386,0.002760192,0.00001542509,0.000008500777,0.00001429575,0.00006875764,0.00001246715,0.0007109354],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005731715,"threshold_uncertainty_score":0.001917422,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006048373898643203,"score_gpt":0.2309007810421391,"score_spread":0.2248524071434959,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}