{"id":"W2295115296","doi":"10.1107/s1600536813032674","title":"1,1′-(Diselanediylbis{[<i>P</i>,<i>P</i>-diphenyl-<i>N</i>-(trimethylsilyl)phosphorimidoyl]methanylylidene})bis[1,1-diphenyl-<i>N</i>-(trimethylsilyl)-λ<sup>5</sup>-phosphanamine] pentane disolvate","year":2013,"lang":"en","type":"article","venue":"Acta Crystallographica Section E Structure Reports Online","topic":"Crystal structures of chemical compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Intramolecular force; Chemistry; Intermolecular force; Hydrogen bond; Solvent; Trimethylsilyl; Alkane stereochemistry; Molecule; Crystallography; Crystallization; Pentane; Crystal (programming language); Crystal structure; Stereochemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","research_integrity"],"category_scores_codex":[0.0007016878,0.003035654,0.00288394,0.001094418,0.001138399,0.000959901,0.002116174,0.002403722,0.02287205],"category_scores_gemma":[0.001226506,0.002880141,0.001879579,0.003486577,0.001268378,0.001925008,0.00117248,0.004216199,0.000001568961],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000773026,"about_ca_system_score_gemma":0.0005415539,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003208521,"about_ca_topic_score_gemma":0.0003739774,"domain_scores_codex":[0.9847828,0.000280629,0.004285669,0.004180751,0.003239881,0.003230245],"domain_scores_gemma":[0.9884466,0.0008748639,0.002717098,0.004302996,0.001584998,0.002073447],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0003924463,0.0006794484,0.01201489,0.0005507795,0.001065954,0.0003257257,0.0002024579,0.000782586,0.9618821,0.000009618189,0.01990717,0.002186899],"study_design_scores_gemma":[0.003713215,0.0004738035,0.008802305,0.0003648262,0.001252238,0.005538776,0.0009797798,0.001194175,0.01964083,0.01192994,0.9411329,0.004977239],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9810581,0.00326718,0.0002960085,0.001065625,0.002073961,0.001617054,0.0009644036,0.002245914,0.007411731],"genre_scores_gemma":[0.9812443,0.000687092,0.004037069,0.0006525083,0.003258071,0.00025545,0.004639921,0.0006638743,0.004561752],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.9422412,"threshold_uncertainty_score":0.9988914,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006169408465259822,"score_gpt":0.2218062472687871,"score_spread":0.2156368388035273,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}