{"id":"W2295115296","doi":"10.1107/s1600536813032674","title":"1,1′-(Diselanediylbis{[<i>P</i>,<i>P</i>-diphenyl-<i>N</i>-(trimethylsilyl)phosphorimidoyl]methanylylidene})bis[1,1-diphenyl-<i>N</i>-(trimethylsilyl)-λ<sup>5</sup>-phosphanamine] pentane disolvate","year":2013,"lang":"en","type":"article","venue":"Acta Crystallographica Section E Structure Reports Online","topic":"Crystal structures of chemical compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Intramolecular force; Chemistry; Intermolecular force; Hydrogen bond; Solvent; Trimethylsilyl; Alkane stereochemistry; Molecule; Crystallography; Crystallization; Pentane; Crystal (programming language); Crystal structure; Stereochemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006854931,0.0002127932,0.00016807,0.000104895,0.0001405535,0.0002001243,0.000294557,0.0001485548,0.0049885],"category_scores_gemma":[0.00007124555,0.0001090054,0.00007368333,0.0001563504,0.0001550162,0.000237859,0.0001831978,0.0002420611,0.00145932],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002129148,"about_ca_system_score_gemma":0.000192319,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005298682,"about_ca_topic_score_gemma":0.001066225,"domain_scores_codex":[0.9999408,0.000006796884,0.000003244776,0.00001949578,0.00001183878,0.00001790295],"domain_scores_gemma":[0.9999739,0.00000362691,0.000007923334,0.000002877262,0.000003563611,0.000008163022],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001647527,0.00001646488,0.0002414471,0.0001203235,0.000005192999,0.0001022746,0.00002071044,0.0001215734,0.9941781,0.0005176558,0.0002826669,0.004228932],"study_design_scores_gemma":[0.0000349299,0.0003766815,0.00183092,0.00000819345,0.000009945969,0.0003776629,0.00004826569,0.0004148763,0.977161,0.00009399039,0.01963666,0.000006809167],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.97062,0.002609192,0.006389264,0.0001749628,0.00009935976,0.00003793636,0.0006253733,0.0003173768,0.01912651],"genre_scores_gemma":[0.9846994,0.001280715,0.00249875,0.00006579485,0.00001023759,0.00002162783,0.0006244704,0.00005007652,0.01074888],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0049885,"threshold_uncertainty_score":0.01668817,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006169408465259822,"score_gpt":0.2218062472687871,"score_spread":0.2156368388035273,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}