{"id":"W2296312673","doi":"10.1002/anie.201508781","title":"Thiophene‐<i>S</i>,<i>S</i>‐dioxidized Indophenine: A Quinoid‐Type Building Block with High Electron Affinity for Constructing n‐Type Polymer Semiconductors with Narrow Band Gaps","year":2016,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organic Electronics and Photovoltaics","field":"Engineering","cited_by":101,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Thiophene; Stille reaction; Band gap; Comonomer; Semiconductor; Organic semiconductor; Electron affinity (data page); Conjugated system; Polymer; Materials science; Electron mobility; Crystallography; Type (biology); Chemistry; Polymer chemistry; Copolymer; Optoelectronics; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001540477,0.0003127082,0.0002566809,0.0001211286,0.0001016559,0.00007740479,0.0002549796,0.0001534499,0.0001436687],"category_scores_gemma":[0.0000730204,0.0002318055,0.00005760719,0.0002810078,0.00007515556,0.0003653606,0.00002331735,0.0002485167,0.000004999655],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000304244,"about_ca_system_score_gemma":0.0001320786,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002525286,"about_ca_topic_score_gemma":0.00003784726,"domain_scores_codex":[0.9985215,0.00001280274,0.0002813614,0.0003513024,0.0003972008,0.0004358035],"domain_scores_gemma":[0.9990326,0.0001607996,0.0001404896,0.0001907846,0.0003690491,0.0001062761],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000435496,0.00002837981,0.0005281853,0.00003593623,0.000213002,0.000004576335,0.00007209693,0.00008516113,0.9958882,0.0005287571,0.0021785,0.000001668792],"study_design_scores_gemma":[0.002169224,0.0003126951,0.00003284233,0.0001673824,0.00006817434,0.0001174935,0.00003173015,9.482996e-7,0.9939792,0.0005310862,0.002209074,0.0003801921],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972079,0.0002982238,0.00001024992,0.0003106128,0.001087199,0.0002479684,0.0001016817,0.0002287952,0.0005073227],"genre_scores_gemma":[0.9973921,0.0001102857,0.0006481946,0.0001108423,0.001243599,0.00004901643,0.0001606135,0.0000892535,0.0001961256],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001909084,"threshold_uncertainty_score":0.9452755,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006704555887291061,"score_gpt":0.2105375140019563,"score_spread":0.2038329581146653,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}