{"id":"W2296998446","doi":"10.1021/acs.joc.6b00296","title":"<i>De Novo</i> Asymmetric Synthesis of a 6-<i>O</i>-Methyl-<scp>d</scp>-<i>glycero</i>-<scp>l</scp>-<i>gluco</i>-heptopyranose-Derived Thioglycoside for the Preparation of <i>Campylobacter jejuni</i> NCTC11168 Capsular Polysaccharide Fragments","year":2016,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Alberta Glycomics Centre; University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Alberta Glycomics Centre; Alberta Innovates - Health Solutions; Alberta Innovates - Technology Futures","keywords":"Chemistry; Stereochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009753062,0.0004686027,0.0001994889,0.0001467697,0.0001382744,0.0001719745,0.0002728145,0.000202488,0.001272719],"category_scores_gemma":[0.0001077721,0.0001382655,0.0002082584,0.0001917901,0.0001157278,0.0002106915,0.0002384996,0.000574405,0.0007247736],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002891325,"about_ca_system_score_gemma":0.0005472682,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000850684,"about_ca_topic_score_gemma":0.001375402,"domain_scores_codex":[0.9999199,0.000008724944,0.000005248926,0.00001477948,0.00001924177,0.00003216949],"domain_scores_gemma":[0.999945,0.000004214967,0.00001721535,0.000008743189,0.000009034683,0.00001571262],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000614002,0.00004114555,0.0001039503,0.00008381678,0.000007707406,0.0002348188,0.00003632412,0.0004595574,0.9922651,0.0006284691,0.0002115663,0.005866234],"study_design_scores_gemma":[0.00001319455,0.000161659,0.0004857853,0.000004837558,0.000008183828,0.0001995076,0.00001693221,0.0005054032,0.9939908,0.00006162764,0.004543934,0.00000817754],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9281261,0.001321714,0.04529923,0.0003431125,0.0001661459,0.0002253146,0.001536847,0.0002986641,0.02268273],"genre_scores_gemma":[0.9728267,0.001406611,0.01959318,0.00007811745,0.00002503863,0.00007719838,0.001015841,0.00007114324,0.004906076],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001272719,"threshold_uncertainty_score":0.004257619,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009182515249877616,"score_gpt":0.2255471740698018,"score_spread":0.2163646588199242,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}