{"id":"W2297100904","doi":"10.1039/c6cy00331a","title":"Continuous flow Negishi cross-couplings employing silica-supported Pd-PEPPSI–IPr precatalyst","year":2016,"lang":"en","type":"article","venue":"Catalysis Science & Technology","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":72,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University; Toronto Public Health","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Negishi coupling; Alkyne; Chemistry; Continuous flow; Azide; Catalysis; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000272509,0.0008177434,0.0004210756,0.0003562931,0.0003470949,0.0002675053,0.0006713258,0.0003943288,0.003558582],"category_scores_gemma":[0.000231959,0.0004867745,0.0002446068,0.0002882803,0.000289807,0.0003988867,0.0003318685,0.001084388,0.003051274],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003995197,"about_ca_system_score_gemma":0.0003601587,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004985185,"about_ca_topic_score_gemma":0.001324063,"domain_scores_codex":[0.9998056,0.00001753056,0.00001564724,0.0000560579,0.00006564855,0.00003952224],"domain_scores_gemma":[0.9998767,0.00002468179,0.00002987978,0.00002741117,0.00002011017,0.0000210874],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005497748,0.00001651424,0.00003238139,0.0001163787,0.000007356481,0.0001345307,0.00002947954,0.00008114389,0.9966091,0.0003275083,0.0001763435,0.002414237],"study_design_scores_gemma":[0.000006975864,0.00006866067,0.0002033518,0.00000383372,0.000007747252,0.0001479712,0.000005086169,0.0001610323,0.9952469,0.00004678353,0.004094969,0.000006617956],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8311151,0.005959954,0.1290533,0.0004252523,0.0002605887,0.0006439443,0.00251985,0.003669827,0.02635207],"genre_scores_gemma":[0.9120445,0.005091151,0.05646348,0.0001535598,0.0000915311,0.000348556,0.002423909,0.0004460863,0.02293726],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003558582,"threshold_uncertainty_score":0.0119046,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01113846537922313,"score_gpt":0.2828797040833712,"score_spread":0.271741238704148,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}