{"id":"W2297396148","doi":"10.1093/jaoac/84.6.1770","title":"Liquid Chromatography/Electrospray Ionization/Isotopic Dilution Mass Spectrometry Analysis of n-(Phosphonomethyl) Glycine and Mass Spectrometry Analysis of Aminomethyl Phosphonic Acid in Environmental Water and Vegetation Matrixes","year":2001,"lang":"en","type":"article","venue":"Journal of AOAC International","topic":"Pesticide and Herbicide Environmental Studies","field":"Environmental Science","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of Environment","funders":"","keywords":"Chemistry; Aminomethylphosphonic acid; Isotope dilution; Chromatography; Mass spectrometry; Glyphosate; Derivatization; Electrospray ionization; Chloroformate; Metabolite","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004855795,0.0002183088,0.0006738413,0.001680275,0.0000656099,0.00002598459,0.0002222123,0.00008780926,0.002184163],"category_scores_gemma":[0.0000350433,0.0001827506,0.0002826822,0.001774188,0.0003180871,0.0004335023,0.0001202522,0.0001884904,0.000003716689],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004389727,"about_ca_system_score_gemma":0.00000674812,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001359744,"about_ca_topic_score_gemma":0.0001031144,"domain_scores_codex":[0.9977826,0.00006780608,0.0009299093,0.0003021912,0.0006630009,0.0002544927],"domain_scores_gemma":[0.999034,0.00008721318,0.0006254209,0.0001453206,0.00001902947,0.00008895213],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"observational","study_design_gemma":"observational","study_design_scores_codex":[0.0001522527,0.0001389176,0.5873199,0.000006047962,0.001830493,0.00001057231,0.0002655647,0.003037442,0.4070178,0.00002449687,0.000002720292,0.0001938454],"study_design_scores_gemma":[0.0006755532,0.0004149141,0.8940943,0.00001626797,0.001592486,0.000014602,0.00021287,0.002569233,0.09991663,0.0002959186,0.00004087982,0.0001563534],"study_design_candidate":"observational","study_design_consensus":"observational","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9898575,0.001846408,0.00763799,0.0001850605,0.00008417939,0.0001000258,0.000025949,0.000004338176,0.000258566],"genre_scores_gemma":[0.9924285,0.003181655,0.004194425,0.00003554015,0.00003318598,0.00000404134,0.00006387502,0.00001188645,0.00004685457],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3071012,"threshold_uncertainty_score":0.998728,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004529737914629825,"score_gpt":0.214767169438445,"score_spread":0.2102374315238152,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}