{"id":"W2297465350","doi":"10.1021/jacs.6b00710","title":"Enabling and Probing Oxidative Addition and Reductive Elimination at a Group 14 Metal Center: Cleavage and Functionalization of E–H Bonds by a Bis(boryl)stannylene","year":2016,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":191,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Australian Research Council; Natural Sciences and Engineering Research Council of Canada; John Fell Fund, University of Oxford; Leverhulme Trust; Engineering and Physical Sciences Research Council; Directorate-General for Research and Innovation; National Marine Sanctuary Foundation","keywords":"Chemistry; Oxidative addition; Reductive elimination; Stoichiometry; Cleavage (geology); Metal; Bond cleavage; Oxidative phosphorylation; Medicinal chemistry; Ammonia; Redox; Stereochemistry; Center (category theory); Surface modification; Crystallography; Inorganic chemistry; Organic chemistry; Catalysis; Physical chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001534831,0.0001407777,0.000262017,0.00001409284,0.00009354942,0.00001770652,0.00008831007,0.00007752804,0.00005787925],"category_scores_gemma":[0.0001584727,0.00009143202,0.0001009847,0.0001255427,0.0005741994,0.00019951,0.0001265193,0.0001676584,1.003119e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000213605,"about_ca_system_score_gemma":0.00002995484,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003646386,"about_ca_topic_score_gemma":2.887229e-7,"domain_scores_codex":[0.9990699,0.00002623185,0.0003164122,0.0001946022,0.000256141,0.0001366756],"domain_scores_gemma":[0.9987674,0.0001351222,0.0007823472,0.00009542841,0.0001288415,0.00009090653],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001185944,0.00006951902,0.00153211,0.00006551572,0.000114295,2.943376e-7,0.000454119,9.950045e-8,0.9924944,0.00001096688,0.002223752,0.00291633],"study_design_scores_gemma":[0.0008999504,0.00005325699,0.0007357608,0.0001417123,0.00008897709,0.00008658398,0.001121943,0.00001673572,0.9959798,0.00006120214,0.0007027484,0.0001113005],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9981397,0.0004032177,0.0001545765,0.001079338,0.00002231649,0.0000382214,0.00008849065,0.00000918174,0.00006490711],"genre_scores_gemma":[0.9986694,0.0006183921,0.0003542044,0.0001064637,0.000115747,0.000002372352,0.0000121271,0.00001674315,0.0001045041],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003485424,"threshold_uncertainty_score":0.372849,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006171746545732576,"score_gpt":0.2140506906123232,"score_spread":0.2078789440665906,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}