{"id":"W2300306696","doi":"10.1021/acs.organomet.5b00967","title":"Transfer Hydrogenation of Nitriles, Olefins, and <i>N</i>-Heterocycles Catalyzed by an <i>N</i>-Heterocyclic Carbene-Supported Half-Sandwich Complex of Ruthenium","year":2016,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":91,"is_retracted":false,"has_abstract":true,"ca_institutions":"Regional Municipality of Niagara; Brock University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Carbene; Chemoselectivity; Catalysis; Quinoline; Transfer hydrogenation; Ruthenium; Medicinal chemistry; Hydride; Conjugated system; Acetone; Organic chemistry; Benzonitrile; Metal","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000121732,0.0004397392,0.0002504426,0.00009699361,0.00008393239,0.0001443263,0.0004002637,0.0002833893,0.000803121],"category_scores_gemma":[0.0001152235,0.0001458731,0.0001977861,0.00007266464,0.0001037335,0.0002859808,0.0002587955,0.0003344609,0.0002425471],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001577338,"about_ca_system_score_gemma":0.0001286317,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00029286,"about_ca_topic_score_gemma":0.0006486152,"domain_scores_codex":[0.9999151,0.0000114825,0.000005897886,0.00002133486,0.00001915413,0.00002707964],"domain_scores_gemma":[0.9999529,0.000008795444,0.00001489001,0.000005513541,0.000006330566,0.0000115173],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000607092,0.00001109079,0.00005715963,0.00004048735,0.000007311068,0.00004158678,0.00001347354,0.00008711025,0.9986203,0.00008916767,0.0000247909,0.0009468352],"study_design_scores_gemma":[0.000004514704,0.0001083181,0.0002866791,0.000002058616,0.000006303438,0.00005796572,0.000006864186,0.0005052245,0.9987434,0.00001166943,0.0002642848,0.000002769782],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960741,0.0005405758,0.001712396,0.00002376679,0.00001469215,0.00001068748,0.000049283,0.00005308879,0.001521392],"genre_scores_gemma":[0.9979141,0.0002543766,0.0008368653,0.00001021972,0.000003661768,0.000007800293,0.00009539313,0.000009858604,0.0008676255],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000803121,"threshold_uncertainty_score":0.002686679,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01391377096131563,"score_gpt":0.2232400887338934,"score_spread":0.2093263177725778,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}