{"id":"W2300402706","doi":"10.1021/acs.organomet.5b00674","title":"Tetracarbonyl(trifluoromethyl)cobalt(I) [Co(CO)<sub>4</sub>(CF<sub>3</sub>)] as a Precursor to New Cobalt Trifluoromethyl and Difluorocarbene Complexes","year":2015,"lang":"en","type":"article","venue":"Organometallics","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canada Foundation for Innovation; University of Ottawa","keywords":"Difluorocarbene; Trifluoromethyl; Chemistry; Cobalt; Carbene; Denticity; Medicinal chemistry; Reactivity (psychology); Phosphine; Fluoride; IMes; Stereochemistry; Metal; Catalysis; Organic chemistry; Inorganic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001101696,0.0003359978,0.0002041076,0.0001432428,0.0001572996,0.000238546,0.0004075916,0.0003662301,0.001484085],"category_scores_gemma":[0.000189046,0.0001544326,0.0001350774,0.0001479626,0.0001715517,0.000235686,0.000217259,0.00034514,0.0004335764],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003951497,"about_ca_system_score_gemma":0.0001578061,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007250924,"about_ca_topic_score_gemma":0.001434776,"domain_scores_codex":[0.9998667,0.00001898201,0.000008669779,0.0000269075,0.00003200566,0.00004665091],"domain_scores_gemma":[0.9999114,0.0000129799,0.00003095997,0.000009101799,0.00001494006,0.00002064282],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009654009,0.00002349605,0.0001031148,0.00009583715,0.000007215594,0.00008901947,0.00003877884,0.0001996174,0.9954917,0.000366895,0.0002173964,0.003270262],"study_design_scores_gemma":[0.00001210083,0.00009695328,0.0003344361,0.000003650711,0.000009863662,0.0001253739,0.000007909705,0.0003000949,0.9944302,0.00002523371,0.004649271,0.000004918335],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9567559,0.004408694,0.02469581,0.0002273184,0.0001123421,0.0001262515,0.0004426319,0.0003929854,0.0128381],"genre_scores_gemma":[0.9856916,0.000870089,0.009091537,0.00006157168,0.00001587736,0.00003898305,0.0002699874,0.00007110104,0.003889194],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001484085,"threshold_uncertainty_score":0.004964769,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08298530233874271,"score_gpt":0.3824787863842969,"score_spread":0.2994934840455542,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}