{"id":"W2300575345","doi":"10.14288/1.0061128","title":"Exploring and exploiting Ruthenium-porphyrin complexes : functionalization, atropisomerism, small-molecule recognition, catalysis, and biological implications","year":2010,"lang":"en","type":"article","venue":"Open Collections","topic":"Axial and Atropisomeric Chirality Synthesis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Porphyrin; Surface modification; Ruthenium; Chemistry; Catalysis; Atropisomer; Combinatorial chemistry; Small molecule; Molecular recognition; Molecule; Nanotechnology; Photochemistry; Organic chemistry; Materials science; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["sts","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001066764,0.0001881453,0.000245373,0.0000600268,0.002749034,0.0006802994,0.0001959561,0.00008519104,0.001756129],"category_scores_gemma":[0.0002247888,0.0001818306,0.000061755,0.0005377225,0.0001921067,0.0003249501,0.000262913,0.0002244939,0.00001047269],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002690949,"about_ca_system_score_gemma":0.00005072532,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003340901,"about_ca_topic_score_gemma":0.001225761,"domain_scores_codex":[0.9988531,0.00003298484,0.0003318183,0.0004738562,0.00008310736,0.0002251003],"domain_scores_gemma":[0.9991122,0.0002051942,0.0001324068,0.0002625078,0.0001364118,0.0001512483],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0002259178,0.00120978,0.05535164,0.0002203281,0.0008185763,0.000008458723,0.002018178,0.00001452724,0.8472297,0.006378268,0.01711487,0.06940974],"study_design_scores_gemma":[0.007789982,0.000571522,0.1385757,0.0004402664,0.001370185,0.00143978,0.02408135,0.0009875488,0.3088494,0.08896232,0.420636,0.006295925],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9656047,0.00005610788,0.001497622,0.001006114,0.0001247017,0.000257971,0.0001745758,0.0001593259,0.03111891],"genre_scores_gemma":[0.9814602,0.0004789556,0.004987665,0.0001536016,0.0004556417,0.001142506,0.0004439949,0.00004524264,0.0108322],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5383803,"threshold_uncertainty_score":0.9991564,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1238650315892854,"score_gpt":0.2569978866041639,"score_spread":0.1331328550148785,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}