{"id":"W2301637861","doi":"10.1021/acs.macromol.5b01607","title":"Push–Pull Porphyrin-Containing Polymers: Materials Exhibiting Ultrafast Near-IR Photophysics","year":2015,"lang":"en","type":"article","venue":"Macromolecules","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Natural Sciences and Engineering Research Council of Canada; China Scholarship Council; Centre québécois sur les matériaux fonctionnels","keywords":"Photochemistry; Time-dependent density functional theory; Porphyrin; Singlet state; Density functional theory; Maleimide; Acceptor; Chemistry; Excited state; Conjugated system; Polymer; Polymer chemistry; Computational chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001103877,0.0004306788,0.0001445521,0.0001994783,0.0001217683,0.0002934416,0.0002531557,0.0002977109,0.0009801114],"category_scores_gemma":[0.0001405029,0.0001916536,0.0001408423,0.0002091214,0.0001510437,0.0002953911,0.0001927785,0.0004083015,0.000327698],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002509044,"about_ca_system_score_gemma":0.0001284042,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002022574,"about_ca_topic_score_gemma":0.0003411361,"domain_scores_codex":[0.9999434,0.000006579082,0.00000399737,0.00001484222,0.00001473198,0.00001633346],"domain_scores_gemma":[0.9999084,0.0000154921,0.00003343761,0.0000117615,0.000009325357,0.00002148932],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001140284,0.00003330132,0.000104341,0.00008861706,0.000006640008,0.00002934585,0.00001623799,0.0002712675,0.996493,0.0002080731,0.0000550197,0.002580061],"study_design_scores_gemma":[0.00001886397,0.0002735541,0.001029134,0.000003527685,0.0000131507,0.00006337427,0.000007279119,0.0006485609,0.9966382,0.00003525796,0.001263102,0.000005962078],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.996165,0.0003629991,0.001991794,0.00003179461,0.000009271964,0.00003808675,0.0001749431,0.00008027113,0.001145818],"genre_scores_gemma":[0.9931121,0.0003903738,0.004254095,0.000021256,0.000006315659,0.00007352194,0.0001706384,0.00002614699,0.001945473],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009801114,"threshold_uncertainty_score":0.003278792,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02289917598059249,"score_gpt":0.2472313999483687,"score_spread":0.2243322239677762,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}