{"id":"W2301902087","doi":"10.1039/c6dt00358c","title":"Evidence for 5d-σ and 5d-π covalency in lanthanide sesquioxides from oxygen K-edge X-ray absorption spectroscopy","year":2016,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Lanthanide and Transition Metal Complexes","field":"Materials Science","cited_by":50,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Light Source (Canada); Saskatoon Medical Imaging","funders":"Basic Energy Sciences; Lawrence Berkeley National Laboratory; Western Economic Diversification Canada; Natural Sciences and Engineering Research Council of Canada; Canadian Institutes of Health Research; Office of Science; Canadian Light Source; U.S. Department of Energy","keywords":"Lanthanide; X-ray absorption spectroscopy; Oxygen; Absorption spectroscopy; Spectroscopy; Absorption (acoustics); Chemistry; Absorption edge; Materials science; Inorganic chemistry; Physics; Band gap; Optoelectronics; Ion; Optics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002500239,0.0002682758,0.0001753502,0.0005426298,0.0003263882,0.0004029144,0.0003269749,0.0003896488,0.001908896],"category_scores_gemma":[0.0003580183,0.0002414396,0.0001214572,0.000374117,0.0006098403,0.0003008311,0.0004448487,0.0003090874,0.0001303662],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002375059,"about_ca_system_score_gemma":0.0001736898,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005533511,"about_ca_topic_score_gemma":0.001310907,"domain_scores_codex":[0.999869,0.00002312169,0.00001701288,0.00002273246,0.00004071974,0.00002735828],"domain_scores_gemma":[0.9998691,0.00003903768,0.00003602557,0.00001651006,0.0000225082,0.00001677831],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001964812,0.00001530511,0.004400664,0.0001111085,0.00001375476,0.0001954205,0.0001428514,0.0002013177,0.9911178,0.001042504,0.0000475479,0.002515284],"study_design_scores_gemma":[0.00004682424,0.0002769084,0.04732808,0.00003095023,0.00005250251,0.0007895452,0.0006160266,0.00233755,0.9447309,0.001606814,0.002160604,0.00002326894],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978049,0.0002742371,0.0006905152,0.00004991582,0.000004186864,0.000004286152,0.00005300696,0.00001276374,0.001106068],"genre_scores_gemma":[0.9990497,0.0001487722,0.0003853496,0.00002431108,0.000001201274,0.000006346649,0.00008509541,0.000004705476,0.0002945255],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001908896,"threshold_uncertainty_score":0.006385922,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06938188890050927,"score_gpt":0.2937278379508486,"score_spread":0.2243459490503393,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}