{"id":"W2309087841","doi":"10.1021/acs.cgd.6b00137","title":"Exploring the Effect of Temperature on a Mechanochemical Reaction by in Situ Synchrotron Powder X-ray Diffraction","year":2016,"lang":"en","type":"article","venue":"Crystal Growth & Design","topic":"X-ray Diffraction in Crystallography","field":"Materials Science","cited_by":119,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"","keywords":"Synchrotron; Powder diffraction; Diffraction; In situ; X-ray crystallography; Mechanochemistry; Reaction mechanism; X-ray; Chemistry; Reaction rate; Chemical engineering; Materials science; Crystallography; Catalysis; Organic chemistry; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003020672,0.0003153867,0.0004213857,0.0001365387,0.000199051,0.0005092858,0.000371057,0.0002479216,0.001372494],"category_scores_gemma":[0.0005005305,0.0002640802,0.0001905218,0.0001994254,0.0005168666,0.0003730461,0.0002138929,0.0004547117,0.0002637911],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00027613,"about_ca_system_score_gemma":0.0001942467,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004479924,"about_ca_topic_score_gemma":0.0004818833,"domain_scores_codex":[0.9997943,0.00002528367,0.00001306621,0.00005464039,0.00007476273,0.00003789301],"domain_scores_gemma":[0.9997036,0.0001303598,0.00007763987,0.00003514426,0.00003802713,0.00001522967],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005658211,0.00001452841,0.0002593204,0.00005437963,0.000005237416,0.00003436149,0.00002709633,0.0002387507,0.9981021,0.0001382427,0.00003109973,0.00103815],"study_design_scores_gemma":[0.000007834286,0.0001002296,0.001490964,0.000003633794,0.000006392085,0.00004587805,0.00002709093,0.001854459,0.9954397,0.00005720123,0.0009602366,0.000006339469],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9837154,0.001121917,0.01173075,0.0001129602,0.00003962941,0.00004361431,0.000302513,0.0001425306,0.002790705],"genre_scores_gemma":[0.9912822,0.0007819544,0.006756985,0.00003981537,0.00001239102,0.00003401662,0.000142792,0.00004748817,0.0009021711],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001372494,"threshold_uncertainty_score":0.004591405,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02139409505618517,"score_gpt":0.2349973930941363,"score_spread":0.2136032980379512,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}