{"id":"W2309144986","doi":"10.1002/chem.201505097","title":"Total Synthesis, Stereochemical Assignment, and Field‐Testing of the Sex Pheromone of the Strepsipteran <i>Xenos peckii</i>","year":2016,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Plant and animal studies","field":"Agricultural and Biological Sciences","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"Natural Sciences and Engineering Research Council of Canada; Michael Smith Health Research BC","keywords":"Pheromone; Stereochemistry; Sex pheromone; Enantiomer; Alkene; Chemistry; Biology; Botany; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002587963,0.0004447809,0.0001972228,0.0001626111,0.0002261646,0.0001765609,0.000238478,0.0001335334,0.0007952777],"category_scores_gemma":[0.0001892289,0.0001280083,0.000158377,0.0001996792,0.0001548251,0.0001898915,0.000190069,0.0003590493,0.0002918652],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002362113,"about_ca_system_score_gemma":0.000512088,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007762582,"about_ca_topic_score_gemma":0.001369279,"domain_scores_codex":[0.9998423,0.00002501549,0.00001219521,0.00003873876,0.00004989824,0.00003178538],"domain_scores_gemma":[0.9998903,0.00001253272,0.00002679265,0.00001837483,0.00002855459,0.00002331707],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009448258,0.0000274312,0.0001972349,0.00003244802,0.000006256544,0.00004999227,0.00001596971,0.0001523747,0.9945661,0.0001043912,0.00003228612,0.00472097],"study_design_scores_gemma":[0.00001935274,0.0006173794,0.001808128,0.000001904842,0.00001187461,0.0001279722,0.00001967702,0.0002633565,0.9958456,0.00003073468,0.001248435,0.000005622447],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9863445,0.000439704,0.00881814,0.00003499284,0.00002252413,0.0001289182,0.0005805111,0.00005167357,0.003579107],"genre_scores_gemma":[0.9826617,0.0008742886,0.01297745,0.00005017173,0.0000134533,0.00007753383,0.0009499029,0.00004456047,0.00235093],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007952777,"threshold_uncertainty_score":0.002660453,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03271826050599977,"score_gpt":0.1780914172962843,"score_spread":0.1453731567902845,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}