{"id":"W2309456546","doi":"10.1021/acs.jpcc.5b04609","title":"Reversibility of Ferri-/Ferrocyanide Redox during Operando Soft X-ray Spectroscopy","year":2015,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"X-ray Spectroscopy and Fluorescence Analysis","field":"Physics and Astronomy","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan; Canadian Light Source (Canada)","funders":"King Abdullah University of Science and Technology; Natural Sciences and Engineering Research Council of Canada; Singapore-MIT Alliance for Research and Technology Centre; National Science Foundation","keywords":"Ferrocyanide; Potassium ferrocyanide; Ferricyanide; Redox; Chemistry; X-ray absorption spectroscopy; Inorganic chemistry; Prussian blue; Cyclic voltammetry; Electrochemistry; Ferric; Absorption spectroscopy; Analytical Chemistry (journal); Electrode; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006134447,0.0005284713,0.0004968643,0.0001596028,0.0003102346,0.0006750418,0.0005967168,0.0005549795,0.001216991],"category_scores_gemma":[0.0009635483,0.0003008801,0.0001651139,0.0001822663,0.0006560063,0.000538561,0.0003498022,0.001034955,0.0002778049],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003303086,"about_ca_system_score_gemma":0.0002293776,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003858818,"about_ca_topic_score_gemma":0.0006392767,"domain_scores_codex":[0.9995651,0.00006694308,0.00002701213,0.0000980974,0.0001454791,0.00009733511],"domain_scores_gemma":[0.9995199,0.000216527,0.00007414375,0.00006097811,0.00009468209,0.00003367781],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005709914,0.00001204274,0.0001251588,0.00003383706,0.000003401804,0.0000398855,0.00006028174,0.00003714041,0.9985448,0.0000849407,0.00004763033,0.0009537275],"study_design_scores_gemma":[0.000004783961,0.00004591413,0.0009185143,0.000002888014,0.000003292408,0.00003490828,0.00002885813,0.0005076292,0.9979656,0.0000617102,0.0004220126,0.000003857078],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9908059,0.0005274195,0.006795883,0.0002025326,0.00005297557,0.00003347197,0.0001779507,0.0002494775,0.001154187],"genre_scores_gemma":[0.9953269,0.000368119,0.003035231,0.0000769123,0.00001528454,0.00003857514,0.0001142782,0.00005837991,0.000966269],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001216991,"threshold_uncertainty_score":0.004071176,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01030806691125749,"score_gpt":0.259434227323915,"score_spread":0.2491261604126575,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}