{"id":"W2312247181","doi":"10.1021/om300913d","title":"Synthesis and Reactivity of a Terminal Scandium Imido Complex","year":2012,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":55,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Scandium; Metalation; Medicinal chemistry; Phenylacetylene; Reactivity (psychology); Imide; Ligand (biochemistry); Stereochemistry; Inorganic chemistry; Polymer chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004095928,0.000202729,0.0003840483,0.00003970923,0.00005571131,0.00001635992,0.0001966471,0.0001418329,0.007027727],"category_scores_gemma":[0.0008815863,0.0001983378,0.00007640791,0.0001556739,0.0002171255,0.0001151777,0.0001599042,0.000145214,0.0000170027],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006300453,"about_ca_system_score_gemma":0.00003834786,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002080942,"about_ca_topic_score_gemma":9.713095e-7,"domain_scores_codex":[0.9988911,0.00003556358,0.0002763001,0.0002342934,0.0002195457,0.0003431657],"domain_scores_gemma":[0.9985857,0.000494495,0.0001821761,0.000494763,0.00004849022,0.0001943953],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001615911,0.0001768447,0.00799902,0.0002135925,0.0000527982,0.000001841719,0.0001842246,2.941765e-8,0.9785772,0.00006672274,0.00005403634,0.01265751],"study_design_scores_gemma":[0.0001672462,0.000004750351,0.00651258,0.00002853837,0.0001306813,0.0001650457,0.0002097044,0.00002247338,0.9847771,0.00005362061,0.007718233,0.0002100074],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9729207,0.0001796823,0.0002034025,0.0001199317,0.00005103306,0.00003424873,0.00005476625,0.00005386833,0.02638238],"genre_scores_gemma":[0.9924217,0.00003589299,0.006701288,0.00001835606,0.0001934408,0.000007865186,0.000007806699,0.00004186616,0.0005717808],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0258106,"threshold_uncertainty_score":0.99388,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03588611787407998,"score_gpt":0.2795499023906973,"score_spread":0.2436637845166174,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}