{"id":"W2312247181","doi":"10.1021/om300913d","title":"Synthesis and Reactivity of a Terminal Scandium Imido Complex","year":2012,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":55,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Scandium; Metalation; Medicinal chemistry; Phenylacetylene; Reactivity (psychology); Imide; Ligand (biochemistry); Stereochemistry; Inorganic chemistry; Polymer chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001684395,0.0003115946,0.0002670743,0.0001825543,0.0002037723,0.0002914415,0.0003886209,0.0002818682,0.001151112],"category_scores_gemma":[0.0002527401,0.000176121,0.0001615791,0.0001634878,0.0001635681,0.0001699079,0.0002475572,0.0003734599,0.0004077241],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004108975,"about_ca_system_score_gemma":0.0002861559,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005592324,"about_ca_topic_score_gemma":0.0008038749,"domain_scores_codex":[0.9998592,0.00001531031,0.00001522673,0.00003365861,0.0000456961,0.00003087636],"domain_scores_gemma":[0.9999132,0.00001046475,0.00001730606,0.00001538746,0.00002176296,0.00002177706],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000804198,0.00001235302,0.00009424731,0.00005165602,0.000007767244,0.00007669753,0.00003428553,0.0002537132,0.9973079,0.0005146732,0.00009107406,0.001475315],"study_design_scores_gemma":[0.00001851051,0.0001348422,0.0003338711,0.000003541611,0.000008260536,0.0001199839,0.000007146158,0.0006601412,0.9961607,0.00003393004,0.002511684,0.000007367435],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9850017,0.0007699861,0.00647242,0.00008132763,0.00003215072,0.00005763804,0.0002955651,0.0001120475,0.00717732],"genre_scores_gemma":[0.9884635,0.0005126151,0.006677745,0.00003468562,0.000009223175,0.00003607387,0.0003428304,0.00003197621,0.003891468],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001151112,"threshold_uncertainty_score":0.003850877,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03588611787407998,"score_gpt":0.2795499023906973,"score_spread":0.2436637845166174,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}