{"id":"W2312351993","doi":"10.1021/om700688p","title":"One-Electron Oxidations of the Methyldiphenylphosphonium Cyclopentadienylide Complexes M(η<sup>5</sup>-C<sub>5</sub>H<sub>4</sub>PMePh<sub>2</sub>)(CO)<sub>3</sub> (M = Cr, Mo, W):  Formation and Dimerization of the 17-Electron, Metal-Centered Radicals [M(η<sup>5</sup>-C<sub>5</sub>H<sub>4</sub>PMePh<sub>2</sub>)(CO)<sub>3</sub>]<sup>+</sup>","year":2007,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Crystallography; Electron; Stereochemistry; Physics; Nuclear physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.007778145,0.008151531,0.009644864,0.004337777,0.00529322,0.00230906,0.008208635,0.004419403,0.0007538044],"category_scores_gemma":[0.003523916,0.008015785,0.006402141,0.01327963,0.004906833,0.005897166,0.004007849,0.006822005,0.001150312],"about_ca_system_candidate":true,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.004684899,"about_ca_system_score_gemma":0.002697645,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001868569,"about_ca_topic_score_gemma":0.001144208,"domain_scores_codex":[0.9574579,0.003398518,0.01260055,0.00832886,0.008826275,0.009387882],"domain_scores_gemma":[0.9699615,0.003854795,0.009499853,0.009698821,0.003250083,0.003734966],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001532352,0.005167384,0.001033623,0.002114504,0.006720796,0.00008838461,0.004076555,0.004110318,0.916977,0.0009052641,0.002965275,0.05430858],"study_design_scores_gemma":[0.007969509,0.0009807379,0.007008094,0.001369515,0.00794808,0.0006061625,0.002432251,0.00731073,0.9506752,0.001680769,0.004522288,0.007496663],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9712016,0.004915549,0.006979582,0.001647694,0.000953481,0.007452984,0.003784839,0.001734729,0.001329552],"genre_scores_gemma":[0.970247,0.01410526,0.0005860915,0.001471617,0.00191179,0.001522261,0.007637304,0.002405011,0.0001136381],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04681192,"threshold_uncertainty_score":0.9996274,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01352613186011987,"score_gpt":0.2285910512805147,"score_spread":0.2150649194203948,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}