{"id":"W2312351993","doi":"10.1021/om700688p","title":"One-Electron Oxidations of the Methyldiphenylphosphonium Cyclopentadienylide Complexes M(η<sup>5</sup>-C<sub>5</sub>H<sub>4</sub>PMePh<sub>2</sub>)(CO)<sub>3</sub> (M = Cr, Mo, W):  Formation and Dimerization of the 17-Electron, Metal-Centered Radicals [M(η<sup>5</sup>-C<sub>5</sub>H<sub>4</sub>PMePh<sub>2</sub>)(CO)<sub>3</sub>]<sup>+</sup>","year":2007,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Crystallography; Electron; Stereochemistry; Physics; Nuclear physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001175988,0.0002443292,0.000161934,0.00009914498,0.0001103812,0.0002036818,0.0003213838,0.0003078736,0.001636732],"category_scores_gemma":[0.0002634686,0.0001375838,0.0001152357,0.0001113069,0.0001730821,0.0002067351,0.0002833615,0.0004295011,0.0001648457],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002401237,"about_ca_system_score_gemma":0.0001014945,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002883485,"about_ca_topic_score_gemma":0.0007790427,"domain_scores_codex":[0.9998767,0.00001379082,0.000006540728,0.00002768371,0.00004048173,0.00003466796],"domain_scores_gemma":[0.9999237,0.00001913158,0.00002370589,0.000008023887,0.00001365776,0.00001174126],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001670898,0.0000210205,0.0002715176,0.0000930309,0.000012228,0.00006929906,0.0001002356,0.0001148659,0.9954885,0.0003023471,0.00007341019,0.003286553],"study_design_scores_gemma":[0.000005436877,0.0000992694,0.0008380071,0.000002759704,0.000005111713,0.00004972712,0.00002763809,0.0004100404,0.99809,0.00003717512,0.0004327746,0.000001953081],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9975387,0.0002731414,0.001006779,0.00002985611,0.00001281074,0.0000102181,0.00004012506,0.0000222984,0.001066077],"genre_scores_gemma":[0.997936,0.0001936511,0.0007529963,0.00001563955,0.000002581615,0.00000770458,0.00005120538,0.000007019115,0.001033252],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001636732,"threshold_uncertainty_score":0.005475461,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01352613186011987,"score_gpt":0.2285910512805147,"score_spread":0.2150649194203948,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}