{"id":"W2312408220","doi":"10.1021/cg500905z","title":"Copper(I) Halides (X = Br, I) Coordinated to Bis(arylthio)methane Ligands: Aryl Substitution and Halide Effects on the Dimensionality, Cluster Size, and Luminescence Properties of the Coordination Polymers","year":2014,"lang":"en","type":"article","venue":"Crystal Growth & Design","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":59,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Natural Sciences and Engineering Research Council of Canada; Centre National de la Recherche Scientifique","keywords":"Isostructural; Chemistry; Monoclinic crystal system; Crystallography; Coordination polymer; Ligand (biochemistry); Steric effects; Methane; Ribbon; Metal-organic framework; Halide; Aryl; Stereochemistry; Crystal structure; Inorganic chemistry; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008861884,0.0002291014,0.0001307183,0.0001068353,0.00008888313,0.0001899013,0.0003336549,0.0001629956,0.0008511628],"category_scores_gemma":[0.0001964797,0.0001471089,0.00006459522,0.0001542607,0.0001872132,0.0001234923,0.0001306673,0.0001744157,0.0001276558],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004784097,"about_ca_system_score_gemma":0.0001327073,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001626914,"about_ca_topic_score_gemma":0.002237029,"domain_scores_codex":[0.9998943,0.00001914923,0.000007307624,0.00002252852,0.00002434931,0.00003241952],"domain_scores_gemma":[0.9998987,0.00001726654,0.00004246676,0.000007193593,0.00001095187,0.00002342115],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004421744,0.00001730008,0.0004171886,0.00004236759,0.000006317731,0.00004427168,0.00003200814,0.0003014933,0.9974973,0.00006279931,0.00006831679,0.001068468],"study_design_scores_gemma":[0.00001735315,0.000141986,0.00148806,0.000001875125,0.0000065223,0.00003538655,0.00001044477,0.0008933255,0.9969922,0.000008904,0.000399651,0.000004250805],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9991628,0.000157357,0.0001567266,0.00001207143,0.000002731823,0.0000032063,0.00005138189,0.00003841981,0.0004153432],"genre_scores_gemma":[0.9989907,0.0001107343,0.0003669834,0.000007604287,0.000002073649,0.000005563686,0.00008049484,0.000008740327,0.0004270124],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001626914,"threshold_uncertainty_score":0.003471196,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01660715581744893,"score_gpt":0.2143551585329045,"score_spread":0.1977480027154556,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}