{"id":"W2312408220","doi":"10.1021/cg500905z","title":"Copper(I) Halides (X = Br, I) Coordinated to Bis(arylthio)methane Ligands: Aryl Substitution and Halide Effects on the Dimensionality, Cluster Size, and Luminescence Properties of the Coordination Polymers","year":2014,"lang":"en","type":"article","venue":"Crystal Growth & Design","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":59,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Natural Sciences and Engineering Research Council of Canada; Centre National de la Recherche Scientifique","keywords":"Isostructural; Chemistry; Monoclinic crystal system; Crystallography; Coordination polymer; Ligand (biochemistry); Steric effects; Methane; Ribbon; Metal-organic framework; Halide; Aryl; Stereochemistry; Crystal structure; Inorganic chemistry; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007471513,0.0002579976,0.0003041309,0.0000459263,0.0003154598,0.00008230979,0.0002736285,0.000162114,0.0000344234],"category_scores_gemma":[0.002162391,0.0001520287,0.00006559955,0.0003091792,0.0003671996,0.0001064768,0.0001463665,0.0002108697,0.000004021069],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003518039,"about_ca_system_score_gemma":0.00005056477,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008585172,"about_ca_topic_score_gemma":0.000004822912,"domain_scores_codex":[0.998539,0.0001676572,0.0003374191,0.0004000438,0.0003120384,0.0002438605],"domain_scores_gemma":[0.9974253,0.00168195,0.0001907894,0.0004435963,0.0001421801,0.0001161998],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001132634,0.00006498647,0.000698632,0.0002270791,0.00003818046,4.272179e-7,0.0001709179,0.00001526306,0.9906361,0.006739954,0.0005753107,0.0007199104],"study_design_scores_gemma":[0.0003900142,0.00005983107,0.002210091,0.0006498819,0.00008778681,0.00001407074,0.00009303997,0.0006963577,0.9944138,0.0008965075,0.0002755032,0.0002131261],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9903229,0.0005459326,0.003084001,0.004941314,0.00007145607,0.0005994468,0.000009815693,0.00004939417,0.0003757014],"genre_scores_gemma":[0.9985154,0.00003311034,0.0002024905,0.0006801098,0.00006762708,0.0001214227,0.000003451044,0.00002809356,0.0003483491],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008192407,"threshold_uncertainty_score":0.6199549,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01660715581744893,"score_gpt":0.2143551585329045,"score_spread":0.1977480027154556,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}