{"id":"W2312552898","doi":"10.1021/om200966p","title":"Dual Reactivity of a Stable Zwitterionic N-Heterocyclic Silylene and Its Carbene Complex Probed with Muonium","year":2012,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University; Mount Royal University; TRIUMF","funders":"","keywords":"Muonium; Chemistry; Silylene; Radical; Hyperfine structure; Reactivity (psychology); Carbene; Muon spin spectroscopy; Methylene; Photochemistry; Muon; Crystallography; Computational chemistry; Medicinal chemistry; Atomic physics; Silicon; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001500344,0.0002909182,0.0001517717,0.0002131632,0.0001619819,0.0003000217,0.0002925835,0.0003584929,0.001445944],"category_scores_gemma":[0.0002157568,0.0001315694,0.000119294,0.0001464278,0.0002948643,0.0002078926,0.0001839815,0.0001919323,0.0001170004],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003197476,"about_ca_system_score_gemma":0.0001085234,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006415017,"about_ca_topic_score_gemma":0.0007325983,"domain_scores_codex":[0.9998788,0.00001598102,0.000003353877,0.00003138568,0.00003357427,0.00003690752],"domain_scores_gemma":[0.9999166,0.0000257238,0.00002387841,0.000008804304,0.000009657417,0.00001546459],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001606493,0.00001551627,0.0003461481,0.00004419955,0.00001454586,0.0001045866,0.00006170425,0.0002648182,0.9974088,0.0003774008,0.00003821611,0.001163442],"study_design_scores_gemma":[0.00001582864,0.0003423686,0.001474269,0.000003270607,0.00001325305,0.00006865746,0.00002813449,0.001692508,0.9956875,0.00004725612,0.0006194279,0.000007489179],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9987265,0.0001116051,0.000337209,0.0000123285,0.000002986601,0.000003831453,0.00001870218,0.00001054394,0.0007761964],"genre_scores_gemma":[0.9991586,0.00005480171,0.0002816565,0.000008032932,0.000001577768,0.000003428034,0.00003597039,0.000004069161,0.0004519456],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001445944,"threshold_uncertainty_score":0.004837155,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0276243454075135,"score_gpt":0.2241259210566828,"score_spread":0.1965015756491693,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}