{"id":"W2312975517","doi":"10.1021/om400740p","title":"A New Route to Ruthenium Thiolate Alkylidene Complexes","year":2013,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Ruthenium; Olefin metathesis; Catalysis; Olefin fiber; Aryl; Medicinal chemistry; Metathesis; Migratory insertion; Stereochemistry; Combinatorial chemistry; Organic chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0001890422,0.0003850498,0.0004626536,0.00006617578,0.0001025739,0.0001938015,0.0008107821,0.0002128508,0.08858158],"category_scores_gemma":[0.0004375674,0.0003732991,0.0001522183,0.0004526305,0.00004490652,0.0001598505,0.0003652131,0.0002822916,0.004572594],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001551629,"about_ca_system_score_gemma":0.0001482496,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003072586,"about_ca_topic_score_gemma":0.000009707263,"domain_scores_codex":[0.997926,0.00002709336,0.0004735319,0.0005930925,0.0003801035,0.0006002014],"domain_scores_gemma":[0.9978194,0.0002057727,0.0001323223,0.001106035,0.0001037876,0.0006327152],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000006949378,0.00004218108,0.0005212147,0.00004321603,0.00007889116,0.000004204114,0.0003481753,0.000003337694,0.9790871,0.0002432213,0.003911683,0.01570988],"study_design_scores_gemma":[0.0003669395,0.00001283486,0.0008249115,0.00003304967,0.0000579417,0.00005092374,0.0001777507,0.00003834744,0.9057137,0.001845327,0.09039252,0.0004856951],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.895524,0.0002352,0.01029179,0.003520045,0.0003010156,0.0002555416,0.00003909916,0.0005851333,0.08924814],"genre_scores_gemma":[0.8086734,0.00002807399,0.112822,0.000652006,0.0008757421,0.00004268382,0.00003952788,0.0001925827,0.07667396],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1025302,"threshold_uncertainty_score":0.9998719,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01506102805672824,"score_gpt":0.2491722967862231,"score_spread":0.2341112687294949,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}