{"id":"W2312975517","doi":"10.1021/om400740p","title":"A New Route to Ruthenium Thiolate Alkylidene Complexes","year":2013,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Ruthenium; Olefin metathesis; Catalysis; Olefin fiber; Aryl; Medicinal chemistry; Metathesis; Migratory insertion; Stereochemistry; Combinatorial chemistry; Organic chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000137068,0.0004288435,0.0003082293,0.0002288706,0.0002116295,0.0002903471,0.000696768,0.0003813915,0.00377178],"category_scores_gemma":[0.0001287554,0.0002288333,0.0002022706,0.0001466286,0.0001653771,0.0003549542,0.0004279595,0.0007587691,0.001286003],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003620909,"about_ca_system_score_gemma":0.0002595435,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004245144,"about_ca_topic_score_gemma":0.001056237,"domain_scores_codex":[0.9998566,0.00001632214,0.00001187068,0.00003380837,0.00004466541,0.000036594],"domain_scores_gemma":[0.9999261,0.0000095051,0.00001833645,0.00001527565,0.00001704066,0.00001371766],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006847979,0.00006333557,0.00008573569,0.0001811274,0.00002321034,0.0001668839,0.0001086981,0.0002304895,0.9861506,0.002526185,0.0006748411,0.009720474],"study_design_scores_gemma":[0.00003433712,0.0002240687,0.0003143756,0.000005648391,0.00002018747,0.0002936459,0.0000199837,0.0007130125,0.9791492,0.0002307352,0.01898146,0.00001339265],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8385377,0.00511569,0.09994905,0.001075988,0.0004294481,0.0004314874,0.0009058801,0.002663006,0.05089181],"genre_scores_gemma":[0.9588235,0.001659742,0.01651235,0.0001956041,0.00004253539,0.00008880004,0.0004432624,0.000135646,0.0220985],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00377178,"threshold_uncertainty_score":0.01261789,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01506102805672824,"score_gpt":0.2491722967862231,"score_spread":0.2341112687294949,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}