{"id":"W2313235060","doi":"10.1021/ma402093v","title":"Effect of Side-Chain Length on the Polymer Chain Dynamics of Poly(alkyl methacrylate)s in Solution","year":2013,"lang":"en","type":"article","venue":"Macromolecules","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Side chain; Pyrene; Excimer; Chemistry; Polymer chemistry; Methyl methacrylate; Polymer; Alkyl; Methacrylate; Methyl acrylate; Acrylate; Substituent; Monomer; Glass transition; Fluorescence; Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003692922,0.0006323046,0.0002589271,0.0001758344,0.0001328491,0.0002640256,0.0001641427,0.0003351993,0.001208664],"category_scores_gemma":[0.0009077719,0.0002724004,0.0002653102,0.000178486,0.000224014,0.0004352045,0.0001622125,0.0004199244,0.0002714143],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001783364,"about_ca_system_score_gemma":0.0002278075,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003044153,"about_ca_topic_score_gemma":0.0004799208,"domain_scores_codex":[0.9997808,0.00005473213,0.00002799261,0.00006091978,0.00004287996,0.00003255546],"domain_scores_gemma":[0.9991048,0.0004021038,0.000196372,0.00006619447,0.000100252,0.0001301358],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000354924,0.0000345022,0.00031298,0.00004785247,0.00001171815,0.00004032927,0.00001650243,0.0003163231,0.9972516,0.00002040446,0.00001194883,0.001580805],"study_design_scores_gemma":[0.00001842023,0.0009400186,0.002221292,0.000009947738,0.00003088048,0.00006157638,0.000007045357,0.001121266,0.9951864,0.0000166082,0.0003789374,0.000007730826],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9981894,0.0005279965,0.0005598125,0.00002109698,0.00001123624,0.00001205723,0.00005975035,0.00002117283,0.0005974862],"genre_scores_gemma":[0.99629,0.000748154,0.001869779,0.00004835326,0.00001416164,0.00003040808,0.0001635058,0.00002465261,0.0008110036],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001208664,"threshold_uncertainty_score":0.0040434,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005597498126700272,"score_gpt":0.220803689177707,"score_spread":0.2152061910510067,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}