{"id":"W2313319827","doi":"10.1021/om400871v","title":"Comparison of the Catalytic Activity of [(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)Ru(2,2′-bipyridine)(L)]OTf versus [(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)Ru(6,6′-diamino-2,2′-bipyridine)(L)]OTf (L = labile ligand) in the Hydrogenation of Cyclohexanone. Evidence for the Presence of a Metal–Ligand Bifunctional Mechanism under Acidic Conditions","year":2013,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University; University of Guelph","funders":"","keywords":"Chemistry; Steric effects; Ruthenium; Ligand (biochemistry); Bipyridine; Amine gas treating; Protonation; Reactivity (psychology); Bifunctional; Catalysis; Substituent; Medicinal chemistry; Stereochemistry; Cyclohexanone; Crystal structure; Crystallography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002362304,0.0002441453,0.0002708714,0.0001637899,0.00008230582,0.0003560503,0.000393373,0.000454262,0.001184706],"category_scores_gemma":[0.0005063725,0.0001185282,0.0001357947,0.0002049426,0.0001888619,0.000182087,0.0001077635,0.0002811404,0.0002446913],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002641499,"about_ca_system_score_gemma":0.0001109943,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001253648,"about_ca_topic_score_gemma":0.001490206,"domain_scores_codex":[0.9998109,0.00003405268,0.00001452284,0.00004087974,0.00005062321,0.00004899201],"domain_scores_gemma":[0.9997794,0.00008512889,0.00004449586,0.00002250268,0.00002729108,0.00004118826],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003879641,0.00003426036,0.0002816406,0.00007317532,0.00001343509,0.00003763726,0.00003483309,0.0002383858,0.9960096,0.00007117296,0.00004554856,0.002772328],"study_design_scores_gemma":[0.00001023322,0.0002528623,0.001823075,0.000003044315,0.000008385687,0.00004816434,0.00001235661,0.001188593,0.9963462,0.00000647877,0.0002966701,0.000003911759],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9970584,0.0006209243,0.001009041,0.00002770305,0.000009732849,0.00001116988,0.0001230477,0.00004636734,0.001093622],"genre_scores_gemma":[0.9978603,0.0002496503,0.0009071355,0.000008008123,0.000003512913,0.000007034518,0.0001726094,0.00001259016,0.0007791085],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001253648,"threshold_uncertainty_score":0.003963232,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04125032988547717,"score_gpt":0.279722697901356,"score_spread":0.2384723680158788,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}