{"id":"W2313324292","doi":"10.1016/j.tetlet.2016.02.111","title":"Silver(I)-mediated regioselective oxidative cross-coupling of phenol and aniline derivatives resulting in 2′-aminobiphenyl-2-ols","year":2016,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":false,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada; Louisiana Board of Regents; CRC Health Group; National Science Foundation","keywords":"Chemistry; Regioselectivity; Aniline; Phenol; Phenols; Oxidative phosphorylation; Oxidative coupling of methane; Amine gas treating; Coupling reaction; Organic chemistry; Medicinal chemistry; Catalysis; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002531084,0.0005807148,0.0001917709,0.0003480238,0.0001690406,0.0002339602,0.0004271452,0.0003742641,0.001514739],"category_scores_gemma":[0.0001574283,0.0003236984,0.0002963264,0.0002422409,0.0002076078,0.0002270594,0.0003358374,0.000482446,0.000634865],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003149053,"about_ca_system_score_gemma":0.000269284,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007819847,"about_ca_topic_score_gemma":0.001940591,"domain_scores_codex":[0.9997739,0.00004003515,0.00001508437,0.00002911267,0.00003239037,0.0001093809],"domain_scores_gemma":[0.9999189,0.00001114794,0.00002193689,0.00001053002,0.00001192119,0.00002548369],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001149576,0.00005496767,0.0001682675,0.0001730449,0.00002281355,0.0004506583,0.0001408045,0.0003753536,0.9907713,0.00130948,0.0003311663,0.006087158],"study_design_scores_gemma":[0.00001098691,0.000145848,0.0009403441,0.000006586275,0.00001541834,0.0001845095,0.0000247566,0.0004522886,0.9955091,0.00009827743,0.002600982,0.00001090134],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9645758,0.001818804,0.01986103,0.0002454098,0.0001567367,0.00006603598,0.0003236498,0.0003811708,0.01257132],"genre_scores_gemma":[0.9921847,0.0008251214,0.003114603,0.0000595958,0.00001031477,0.00001956744,0.0001444908,0.00004127726,0.00360036],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001514739,"threshold_uncertainty_score":0.005067289,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02107614258787421,"score_gpt":0.2904851020528617,"score_spread":0.2694089594649875,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}