{"id":"W2313528577","doi":"10.1021/jz3018013","title":"Two-Dimensional Electronic Spectroscopy Reveals Ultrafast Downhill Energy Transfer in Photosystem I Trimers of the Cyanobacterium <i>Thermosynechococcus elongatus</i>","year":2012,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry Letters","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":43,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Photosystem II; Spectroscopy; Chromophore; Chemical physics; Ultrashort pulse; Photosystem I; Energy transfer; Chemistry; Light-harvesting complex; Purple bacteria; Photochemistry; Ultrafast laser spectroscopy; Photosynthesis; Electron transfer; Photosynthetic reaction centre; Physics; Optics; Laser","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003607795,0.0002859415,0.0005339929,0.00001891999,0.00009904835,0.00001185092,0.0005044845,0.00003837319,0.00008834935],"category_scores_gemma":[0.000009684407,0.0001609196,0.00044297,0.000270136,0.0002225173,0.0001316453,0.0000500481,0.000683206,0.00000182201],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001338936,"about_ca_system_score_gemma":0.00006468467,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007887784,"about_ca_topic_score_gemma":0.000001050798,"domain_scores_codex":[0.9981312,0.0001470138,0.0005424967,0.0001413846,0.0004106671,0.0006272355],"domain_scores_gemma":[0.9989524,0.0002906243,0.0003176456,0.0002761802,0.00005371244,0.0001093599],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002117678,0.000297629,0.002204647,0.00002283404,0.0001788289,5.984214e-7,0.000364386,0.0001516286,0.996107,0.000267187,0.000170648,0.00002285632],"study_design_scores_gemma":[0.0009581441,0.00003513682,0.0009219802,0.0001016124,0.0001328416,0.00001180288,0.0001509777,0.00002158822,0.9970946,0.0002675753,0.0001292083,0.0001745097],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9982042,0.0001344562,0.00009573131,0.0007476849,0.00009248043,0.00009560611,0.00002449363,0.000005763565,0.0005995634],"genre_scores_gemma":[0.9985561,0.000005256263,0.00000838195,0.0002449832,0.001136004,0.000006914193,0.000003458486,0.00002326855,0.00001558603],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001282667,"threshold_uncertainty_score":0.6562111,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004137223183077167,"score_gpt":0.2145747265863902,"score_spread":0.2104375034033131,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}