{"id":"W2313599906","doi":"10.1021/ja107834g","title":"A Beneficial Kinetic Effect of an η<sup>5</sup>-C<sub>5</sub>Me<sub>4</sub>H Ligand","year":2010,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Steric effects; Ligand (biochemistry); Reactivity (psychology); Benzene; Stereochemistry; Kinetic energy; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001610925,0.0003555915,0.0002346384,0.00007726067,0.000133723,0.0002994575,0.000396898,0.0002535965,0.003995901],"category_scores_gemma":[0.0002966648,0.0001561267,0.0001500959,0.00007886675,0.0002474878,0.0002208722,0.0002254606,0.0003183684,0.0009196549],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002820954,"about_ca_system_score_gemma":0.0002229461,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000836176,"about_ca_topic_score_gemma":0.001703226,"domain_scores_codex":[0.9998529,0.0000251678,0.00001061045,0.00003108585,0.00003725566,0.0000428815],"domain_scores_gemma":[0.9998503,0.0000469216,0.00004591787,0.00001853704,0.00001254278,0.00002582075],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005545295,0.00002192051,0.0002150608,0.0001580353,0.00001495782,0.00006644201,0.00002308294,0.0002396368,0.9942363,0.0004399061,0.00019278,0.003837359],"study_design_scores_gemma":[0.00001049461,0.0001623644,0.0007488343,0.000005575369,0.00001118183,0.00009698495,0.0000121519,0.0004164738,0.9955133,0.00002862411,0.002988414,0.000005648615],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9690599,0.002784724,0.01068116,0.0002085088,0.0001212032,0.00005756983,0.0003715073,0.0005614302,0.01615402],"genre_scores_gemma":[0.9936463,0.0003713326,0.002646103,0.00005506674,0.000007657048,0.00001735716,0.0001504504,0.00004554122,0.003060192],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003995901,"threshold_uncertainty_score":0.01336759,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004753519938388502,"score_gpt":0.2157478700181893,"score_spread":0.2109943500798008,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}