{"id":"W2314343067","doi":"10.1021/ic402602d","title":"Zirconium(IV) Metallocavitands As Blue-Emitting Materials","year":2014,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Chemistry; Zirconium; Carboxylate; Photoluminescence; Inorganic chemistry; Nitrogen; Polymer chemistry; Nuclear chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0007551539,0.0002492083,0.0003270276,0.00002503338,0.0001771264,0.0002415246,0.0006306584,0.0001597586,0.0366454],"category_scores_gemma":[0.000766984,0.0002541097,0.00005737252,0.0001635043,0.0001250813,0.0001733229,0.0002701748,0.0001277208,0.001515938],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007815265,"about_ca_system_score_gemma":0.00008161167,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006163094,"about_ca_topic_score_gemma":0.000002161592,"domain_scores_codex":[0.9981285,0.00007556497,0.0004763921,0.0005173646,0.000386822,0.0004153064],"domain_scores_gemma":[0.9986887,0.0001993941,0.0002263561,0.0006249815,0.0001212189,0.0001393334],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000007341685,0.00002607794,0.00004009443,0.00008789311,0.000006455909,0.000003776483,0.00009232591,0.000003385484,0.9975199,0.0004917836,0.001362776,0.0003582669],"study_design_scores_gemma":[0.0003531407,0.00002230982,0.0000942048,0.00002790801,0.00002261824,0.00007486272,0.00006950775,0.00003661931,0.9823252,0.001044928,0.01563359,0.0002951188],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9778796,0.00007536506,0.0006562189,0.0004388832,0.0005883065,0.00009487767,0.00002190251,0.0003034915,0.0199414],"genre_scores_gemma":[0.9926274,0.000004314916,0.001221099,0.0003124584,0.0006165569,0.0000227186,0.00002328357,0.0000420943,0.005130086],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03512947,"threshold_uncertainty_score":0.9999911,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007536807846857572,"score_gpt":0.2285441307917998,"score_spread":0.2210073229449422,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}