{"id":"W2314358254","doi":"10.1021/om2011613","title":"Insertion Reactions of Diazomethanes and Electrophilic Boranes","year":2011,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Diazomethane; Chemistry; Electrophile; Boranes; Trimethylsilyl; Medicinal chemistry; Stereochemistry; Organic chemistry; Boron; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004653262,0.0007162471,0.0003114182,0.000273895,0.0003206817,0.0002822996,0.0004698466,0.0004205006,0.002190182],"category_scores_gemma":[0.0003694788,0.0004213433,0.0003241721,0.0002084501,0.0003646319,0.0005207014,0.000702407,0.0007801426,0.0009831786],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005595869,"about_ca_system_score_gemma":0.0003326185,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004036725,"about_ca_topic_score_gemma":0.001148958,"domain_scores_codex":[0.9996151,0.00008735375,0.00002272574,0.00006777938,0.00008058432,0.0001265053],"domain_scores_gemma":[0.9998857,0.00002623638,0.00002804166,0.00001524751,0.00001308643,0.00003170804],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002034592,0.00002106797,0.00008104672,0.000103706,0.00001511279,0.0001237602,0.0001061377,0.00008908646,0.9950104,0.001688024,0.0001091195,0.002449262],"study_design_scores_gemma":[0.00003848971,0.0001888357,0.000159467,0.000007900699,0.00001133852,0.0002124154,0.00002813578,0.0001951984,0.9937859,0.0001892724,0.00517334,0.000009683545],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9457155,0.005293523,0.02397065,0.0004064821,0.0002187392,0.0001317247,0.000242588,0.000388785,0.02363205],"genre_scores_gemma":[0.9784979,0.002231588,0.01030468,0.000116027,0.00002107283,0.00006327111,0.0001966967,0.00006279525,0.008505792],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002190182,"threshold_uncertainty_score":0.007326841,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02154804706284503,"score_gpt":0.2124253580110433,"score_spread":0.1908773109481982,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}