{"id":"W2314358254","doi":"10.1021/om2011613","title":"Insertion Reactions of Diazomethanes and Electrophilic Boranes","year":2011,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Diazomethane; Chemistry; Electrophile; Boranes; Trimethylsilyl; Medicinal chemistry; Stereochemistry; Organic chemistry; Boron; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00007767142,0.000182888,0.0002517998,0.00007981091,0.00006255059,0.00001326173,0.0001684862,0.0001676458,0.005007959],"category_scores_gemma":[0.0001078435,0.0001809715,0.00006442118,0.00029607,0.0001448283,0.0001331819,0.00005892534,0.0001694702,0.00002544611],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000354657,"about_ca_system_score_gemma":0.0000440095,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008286643,"about_ca_topic_score_gemma":0.00002047389,"domain_scores_codex":[0.9990193,0.00001092773,0.0003253877,0.0002718328,0.0001508833,0.0002216366],"domain_scores_gemma":[0.9992549,0.00004226065,0.000153696,0.0003569754,0.00007240736,0.0001197948],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000233273,0.0001424731,0.01076814,0.0002123005,0.00004997175,0.000003378349,0.0003777804,4.322856e-8,0.9862369,0.0008135142,0.0000136113,0.001358609],"study_design_scores_gemma":[0.0002823214,0.0000266932,0.009504873,0.00001709834,0.00005735125,0.00003886138,0.000176188,0.000003485829,0.9871979,0.0006673008,0.001839459,0.0001884051],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9867281,0.0005515559,0.00001531289,0.00005465598,0.00004182709,0.00003584496,0.00001381607,0.0001034965,0.01245534],"genre_scores_gemma":[0.9982509,0.0004676394,0.0004225613,0.00002380485,0.00006900647,0.000006926675,0.00001945973,0.0000399688,0.0006997443],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01175559,"threshold_uncertainty_score":0.9959016,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02154804706284503,"score_gpt":0.2124253580110433,"score_spread":0.1908773109481982,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}