{"id":"W2314371156","doi":"10.1021/ie501221x","title":"Experimental Determination and Computational Prediction of Androstenedione Solubility in Alcohol + Water Mixtures","year":2014,"lang":"en","type":"article","venue":"Industrial & Engineering Chemistry Research","topic":"Crystallization and Solubility Studies","field":"Materials Science","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"CNIB","keywords":"Solubility; Mole fraction; Methanol; Chemistry; Non-random two-liquid model; Thermodynamics; Ethanol; Alcohol; Binary number; Aqueous solution; Chromatography; Organic chemistry; Physical chemistry; Activity coefficient; Mathematics; Physics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001174117,0.00008101738,0.0001448946,0.00006090282,0.00006639685,0.00003732238,0.00008436795,0.0001167396,0.0001399907],"category_scores_gemma":[0.0004496658,0.00007234946,0.00001830649,0.0001081981,0.0001278744,0.00009437645,0.00008315429,0.0001744061,0.000001464884],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006520623,"about_ca_system_score_gemma":0.00002212969,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004148342,"about_ca_topic_score_gemma":0.000001610235,"domain_scores_codex":[0.998879,0.00006521249,0.0002596238,0.0002230635,0.0003643821,0.0002087632],"domain_scores_gemma":[0.9995144,0.0001777336,0.00002271662,0.0001115174,0.0001194416,0.00005417094],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003220177,0.00004502073,0.002416952,0.00005430574,0.000002253058,5.148467e-7,0.0002943147,0.007341521,0.9895349,0.00000709869,0.00001722185,0.0002536799],"study_design_scores_gemma":[0.0007543651,0.00004091281,0.003175524,0.00003658861,0.00000151504,0.000003296344,0.00008721703,0.04095678,0.9547394,0.00004611731,0.00009947659,0.00005881151],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9993477,0.00003757848,0.0001673666,0.00007291508,0.0000853308,0.0001456244,0.00001839402,0.00002575179,0.00009937888],"genre_scores_gemma":[0.9997042,0.000001761865,0.0000763151,0.000001688242,0.00012615,0.000016719,0.00003258306,0.000005705855,0.00003481127],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03479552,"threshold_uncertainty_score":0.2950325,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08351975382768373,"score_gpt":0.3337323890278616,"score_spread":0.2502126352001778,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}