{"id":"W2314404746","doi":"10.1021/ma3023525","title":"Understanding the Controlled Polymerization of Methyl Methacrylate with Low Concentrations of 9-(4-Vinylbenzyl)-9<i>H</i>-carbazole Comonomer by Nitroxide-Mediated Polymerization: The Pivotal Role of Reactivity Ratios","year":2013,"lang":"en","type":"article","venue":"Macromolecules","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Queen's University","funders":"Centre National de la Recherche Scientifique; Faculty of Engineering, McGill University","keywords":"Comonomer; Nitroxide mediated radical polymerization; Chemistry; Methyl methacrylate; Polymer chemistry; Polymerization; Reactivity (psychology); Copolymer; Styrene; Reaction rate constant; Radical polymerization; Photochemistry; Organic chemistry; Kinetics; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001483555,0.0002573208,0.0001130765,0.00007536059,0.00007114196,0.0002630745,0.00025285,0.0003090636,0.0005845632],"category_scores_gemma":[0.0001913003,0.0001168493,0.0001259089,0.00006622635,0.0002362322,0.0006393422,0.00009660362,0.0004535413,0.0002228186],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003709746,"about_ca_system_score_gemma":0.0002030886,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004630556,"about_ca_topic_score_gemma":0.0005978298,"domain_scores_codex":[0.9999293,0.000007291638,0.000004760664,0.0000248758,0.00001692589,0.00001681373],"domain_scores_gemma":[0.9999218,0.00002054344,0.00003495857,0.000005596343,0.00001054735,0.000006658376],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001175483,0.000007172054,0.0001598618,0.00004018589,0.000001133493,0.00002044956,0.0000133357,0.000135738,0.9985604,0.0002703074,0.00001000833,0.0007696671],"study_design_scores_gemma":[0.000002342636,0.00003926551,0.0009078661,0.000002683525,0.000002640742,0.00004247428,0.00001069022,0.003395652,0.9949882,0.0001075224,0.0004981242,0.000002499265],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9816534,0.001655743,0.01506405,0.0001852112,0.00001873922,0.00001955022,0.00007393347,0.00005762229,0.001271844],"genre_scores_gemma":[0.9953136,0.0008523554,0.003258635,0.00002485705,0.000006612987,0.00001041755,0.0000379271,0.000007543069,0.0004878629],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005845632,"threshold_uncertainty_score":0.002691627,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009149695383430611,"score_gpt":0.201335947251153,"score_spread":0.1921862518677224,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}