{"id":"W2314454852","doi":"10.1021/om300182c","title":"Radical Mechanisms in the Reaction of Organic Halides with Diiminepyridine Cobalt Complexes","year":2012,"lang":"en","type":"article","venue":"Organometallics","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":42,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa; University of Manitoba","funders":"Natural Sciences and Engineering Research Council of Canada; University of Manitoba","keywords":"Chemistry; Aryl; Halide; Halogen; Medicinal chemistry; Alkyl; Pyridine; Radical; Ring (chemistry); Hydrogenolysis; Photochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002695041,0.0003925578,0.0002087726,0.0002139736,0.0002551273,0.00050757,0.0006731507,0.0004110129,0.002311545],"category_scores_gemma":[0.0003085398,0.0001785108,0.0001604769,0.00008844002,0.0004620954,0.0004535029,0.0005174174,0.0004633377,0.0004084989],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005949368,"about_ca_system_score_gemma":0.000185693,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005421819,"about_ca_topic_score_gemma":0.0005911593,"domain_scores_codex":[0.9998345,0.0000197983,0.00000968394,0.00002437212,0.00004047246,0.00007104487],"domain_scores_gemma":[0.999902,0.00002538507,0.00002963997,0.00001270756,0.00001242377,0.00001776941],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007525566,0.0001304291,0.001022786,0.0006702831,0.00006695621,0.0007185816,0.0005261667,0.001754666,0.9763242,0.01024259,0.0004786233,0.007312127],"study_design_scores_gemma":[0.0000829658,0.0002813724,0.0005893942,0.0000123833,0.000025482,0.0001740315,0.00008160541,0.00220863,0.9926887,0.0007313514,0.003106394,0.00001779455],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9876816,0.001837199,0.004649558,0.0002744625,0.00008636633,0.00007181343,0.00008851611,0.0001669865,0.005143424],"genre_scores_gemma":[0.9966388,0.0004830503,0.0006544489,0.00003378597,0.00001003249,0.00001812156,0.00004614578,0.0000106734,0.002104893],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002311545,"threshold_uncertainty_score":0.007732928,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03085626241636807,"score_gpt":0.2692629083803327,"score_spread":0.2384066459639647,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}