{"id":"W2314464106","doi":"10.1021/ja306025d","title":"Ruthenium-Catalyzed Aldehyde Functionality Reshuffle: Selective Synthesis of<i>E</i>-2-Arylcinnamaldehydes from<i>E-</i>β-Bromostyrenes and Aryl Aldehydes","year":2012,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Aldehyde; Chemistry; Aryl; Ruthenium; Catalysis; Bromide; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005797519,0.0002792077,0.0007550792,0.00004548123,0.0001516963,0.00002797957,0.0005256761,0.0001288656,0.0001822276],"category_scores_gemma":[0.0007809703,0.0001940837,0.0008919041,0.0008375901,0.000771817,0.0002631581,0.0002276654,0.0005084243,0.000003616162],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002108935,"about_ca_system_score_gemma":0.0001092598,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002126626,"about_ca_topic_score_gemma":0.000001633109,"domain_scores_codex":[0.9978017,0.0000675429,0.0007594093,0.0002441575,0.0007532393,0.0003739889],"domain_scores_gemma":[0.9964047,0.001066323,0.00158643,0.0003915315,0.0002854301,0.0002655726],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002217649,0.0003393281,0.06637599,0.00004656082,0.001233867,6.420425e-7,0.0007226756,0.000005932578,0.9209024,0.00002647488,0.004435652,0.005688664],"study_design_scores_gemma":[0.0004427685,0.00001609802,0.007723596,0.00005975996,0.0006092059,0.00005277915,0.001337253,0.00009306341,0.9872863,0.0002981809,0.001841147,0.0002398735],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9966089,0.001467591,0.0001071273,0.0009551426,0.00008903939,0.00004324281,0.0001077063,0.00002414078,0.000597164],"genre_scores_gemma":[0.9968789,0.0003753242,0.001764347,0.0003448975,0.0005209096,0.000008021006,0.00001159194,0.00003098847,0.00006503015],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06638382,"threshold_uncertainty_score":0.7914503,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009574860144642972,"score_gpt":0.235688561885621,"score_spread":0.226113701740978,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}