{"id":"W2314565131","doi":"10.1021/la403425d","title":"Facile Functionalization of PDMS Elastomer Surfaces Using Thiol–Ene Click Chemistry","year":2013,"lang":"en","type":"article","venue":"Langmuir","topic":"Innovative Microfluidic and Catalytic Techniques Innovation","field":"Engineering","cited_by":92,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Surface modification; Click chemistry; Ethylene glycol; Chemistry; Titration; Ene reaction; Nucleophile; Polydimethylsiloxane; Polymer chemistry; Maleic anhydride; Thiol; Elastomer; Organic chemistry; Chemical engineering; Polymer; Copolymer; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006759883,0.0000926634,0.0001073754,0.00004330009,0.00002986868,0.00001061756,0.00006762884,0.000083331,0.000518495],"category_scores_gemma":[0.000007664355,0.00008981665,0.00002273835,0.0003230512,0.00003576291,0.0001309768,0.0000181769,0.00007483026,0.00003223584],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005026034,"about_ca_system_score_gemma":0.000009191612,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003837513,"about_ca_topic_score_gemma":9.317771e-8,"domain_scores_codex":[0.9994823,0.000004604303,0.0002073501,0.00008759591,0.0001047877,0.0001133278],"domain_scores_gemma":[0.9996769,0.000008030005,0.00004756113,0.0001065447,0.000149335,0.00001158873],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000001234876,0.000008666413,0.001031015,0.00008353041,0.00001896006,1.651102e-7,0.00008308873,0.0003888692,0.9872505,0.0005284504,0.009464127,0.001141406],"study_design_scores_gemma":[0.0001120093,0.000006493315,0.003398657,0.00002275437,0.000006625668,0.00000447085,0.00008667855,0.006539885,0.975765,0.0002247044,0.01369839,0.0001343242],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8662071,0.0001853026,0.1247731,0.0000186458,0.000096549,0.000104763,0.00001908453,0.000227158,0.008368283],"genre_scores_gemma":[0.9983111,0.000005686225,0.0009373769,0.00003267245,0.00005808119,0.00001194421,0.000121675,0.00001847136,0.0005029793],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.132104,"threshold_uncertainty_score":0.5677156,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01273704835616352,"score_gpt":0.2171756512569502,"score_spread":0.2044386029007867,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}