{"id":"W2314584427","doi":"10.1021/es504252z","title":"Carbon and Chlorine Isotope Analysis to Identify Abiotic Degradation Pathways of 1,1,1-Trichloroethane","year":2014,"lang":"en","type":"article","venue":"Environmental Science & Technology","topic":"Environmental remediation with nanomaterials","field":"Engineering","cited_by":56,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Chemistry; Kinetic isotope effect; Isotopes of chlorine; Isotope fractionation; Chlorine; Isotope analysis; Isotope; Fractionation; Isotopes of carbon; Stable isotope ratio; Bond cleavage; Environmental chemistry; Organic chemistry; Total organic carbon; Catalysis; Geology; Deuterium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003507804,0.0001440902,0.0002438496,0.0009959881,0.00005925967,0.00001588228,0.000297589,0.00009180207,0.00006865721],"category_scores_gemma":[0.00007780148,0.0001457123,0.00002768502,0.001485542,0.0005231936,0.0001452504,0.0001951232,0.00006797965,0.00002843918],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000206708,"about_ca_system_score_gemma":0.000004774177,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001207941,"about_ca_topic_score_gemma":0.000006612391,"domain_scores_codex":[0.9987672,0.0000129864,0.0002876383,0.0003281254,0.000320341,0.0002837318],"domain_scores_gemma":[0.9994384,0.00002288019,0.00007028801,0.0003365868,0.00000317246,0.0001286487],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000002207965,0.00001867276,0.04049253,0.000005335815,0.00001917831,6.089084e-7,0.00007530676,0.001384954,0.9532059,0.00008099401,9.345826e-7,0.004713345],"study_design_scores_gemma":[0.0001418746,0.00008494415,0.2351277,0.000003739063,0.00005238352,0.000003239328,0.00007589344,0.004454723,0.7596737,0.0001184542,0.0001313274,0.0001319633],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9980984,0.00007741227,0.001076775,0.00008689944,0.000129538,0.000201483,0.000009269923,0.0001167541,0.0002034704],"genre_scores_gemma":[0.9989305,0.00009601712,0.0008744919,0.00002070251,0.00001438177,0.00002175742,0.000007691998,0.00001351572,0.00002093222],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1946352,"threshold_uncertainty_score":0.5941973,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00557260419127005,"score_gpt":0.2056043273016424,"score_spread":0.2000317231103723,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}