{"id":"W2314771244","doi":"10.1021/ac4032466","title":"Chemical Generation of Arsane and Methylarsanes with Amine Boranes. Potentialities for Nonchromatographic Speciation of Arsenic","year":2014,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Arsenic contamination and mitigation","field":"Environmental Science","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"","keywords":"Chemistry; Arsenic; Protonation; Reactivity (psychology); Inorganic chemistry; Ammonia borane; Hydride; Borane; Masking agent; Organic chemistry; Dehydrogenation; Metal; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003340119,0.0004108942,0.0001764488,0.0002085013,0.00009778401,0.0001814255,0.0002878892,0.0003825693,0.001091691],"category_scores_gemma":[0.0003321667,0.000201119,0.0003143403,0.0001323116,0.0001931091,0.0002544454,0.0002433832,0.000372518,0.0004562757],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001615507,"about_ca_system_score_gemma":0.0001175047,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002436139,"about_ca_topic_score_gemma":0.0006215667,"domain_scores_codex":[0.999744,0.00007380026,0.00001538132,0.00006060862,0.00006667127,0.0000396158],"domain_scores_gemma":[0.9997929,0.00006474542,0.00005077582,0.00002855066,0.00004380385,0.00001918202],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000350029,0.000005452015,0.0000445576,0.00005029114,0.000004960315,0.0000114011,0.000009751576,0.00002658277,0.9989236,0.0000509041,0.00001225753,0.0008251468],"study_design_scores_gemma":[0.000003268846,0.00008900117,0.0002248666,0.000001554631,0.000004343674,0.00002773446,0.000005993476,0.0001452567,0.9989529,0.00001042899,0.0005330647,0.000001648511],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9765782,0.002377742,0.01660384,0.0001174873,0.00007276591,0.00009965157,0.0003100733,0.0002212879,0.0036189],"genre_scores_gemma":[0.9841055,0.0009455984,0.01118834,0.0000716223,0.00001957473,0.00004782407,0.0002755636,0.00003825277,0.003307656],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001091691,"threshold_uncertainty_score":0.003652036,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009546903410626585,"score_gpt":0.2089319802581999,"score_spread":0.1993850768475733,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}